Naslov
Charging Behavior and Stability of the Novel Amino Group Containing Cellulose Ester Cellulose-4-[N-methylamino]butyrate Hydrochloride

Autori
Salomao Pinto Zarth, Cintia ; Zemljič Fras, Lidija ; Čakara, Duško ; Bračič, Matej ; Pfeiffer, Annett ; Stana-Kleinschek, Karin ; Heinze, Thomas

Izvornik
Macromolecular chemistry and physics (1022-1352) 213 (2012), 16; 1669-1676

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Aminocellulose ; Titration ; Potentiometric ; Protonation ; Polysaccharide ; Polyelectrolyte ; pK ; Charging

Sažetak
The charging behavior of water-soluble cellulose-4-[ N -methylamino]butyrate hydrochloride (CMABH) with different degree of substitution (DS) is investigated by polyelectrolyte titration at different pH values. Samples of high DS (0.92) and low DS (0.31) exhibit a decrease in positively charged groups from pH 2 (3.9 and 1.9 mmol g − 1 ) to pH 9 (0.81 and 0.65 mmol g − 1 ) due to the deprotonation of the ammonium groups. The stability of the ester linkage of CMABH is examined as a function of pH value and storage time (up to 28 d). A hydrolysis of the ester moiety is evident after 2 h at pH 8, which is also proved by ATR-FTIR- and Raman spectroscopy.

Izvorni jezik
Engleski

Znanstvena područja
Fizika, Kemija

POVEZANOST RADA