Naslov
Transfer of selected hydrogen bonding motifs from organic to metal-organic systems using copper halides

Autori
Penić, Nikolina ; Borovina, Mladen ; Đaković, Marijana

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Solid-state science and research : book of abstracts / Juribašić Kulcsar, Marina ; Halasz, Ivan - Zagreb : Institut Ruđer Bošković, 2017, 94-94

ISBN
978-953-7941-15-4

Skup
Solid-state science and research

Mjesto i datum
Zagreb, Hrvatska, 28.06.2017. - 30.06.2017

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
supramolecular ; hydrogen bonds ; copper(I) ; copper(II) ; pyrazine ; pyrimidone

Sažetak
To be in a position to design crystalline solids with desired properties, as one of the main crystal engineering goals, we firstly need to be able to design crystal structures with predefined topologies. Hydrogen bonds have proven to be an invaluable crystal engineering tool, and a number of supramolecular synthetic strategies to harness their potential have already been developed for purely organic systems. There is a need for similar strategies for metalorganic systems as those give us an access to properties that are generally not available in metal-free settings. Unfortunately, due to dynamic nature of non- covalent interactions, those systems have not yet received any near the same attention. Here, we would like to examine potential transferability of those strategies from pure organic to metal- organic systems. With this in mind, we have prepared a series of copper(I) and copper(II) halide coordination polymers with pyrazine and pyrimidone derivates. We found that the prepared compounds exhibit 1D polymeric chains, usually found in copper(I) and copper(II) halides, along with the hydrogen bond motifs observed in purely organic settings.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA