Naslov
Aromatic C-­Nitroso Compounds and their Dimers: A Model for Physical Organic Chemistry of Reactions in Crystalline Molecular Solids

Autori
Vančik, Hrvoj

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
European Symposium on Organic Reactivity: Book of Abstracts / O'Donoghue, AnnMarie ; Hodgson, David R.W. - Durham, 2017, 87-87

Skup
European Symposium on Organic Reactivity (ESOR 2017)

Mjesto i datum
Durham, Ujedinjeno Kraljevstvo, 03.09.2017. - 08.09.2017

Vrsta sudjelovanja
Predavanje

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
Aromatic C-nitroso compounds ; Dimerization ; Solid-state kinetics

Sažetak
Dimerization of aromatic C-­nitroso compounds and dissociation of the corresponding azodioxy dimers are represented as a model for studying the thermal organic solid-­state reaction mechanisms. Reactivity of the model molecules in solid state is examined under the different topotactic conditions, especially as a function of disordering, surface defects, and phase transformations. The dependence of the reaction rate on the distance between reacting molecules (topochemical effect) is discussed in more detail. The investigation is also extended to the reactions in the condensed one-­ and two-­dimensional molecular arrangements.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA