Naslov
Mechanosynthesis of 4, 4'-bis(N, N-dimethylamino)-azobenzene and its dicyclopalladated complex

Autori
Bjelopetrović, Alen ; Barišić, Dajana ; Lukin, Stipe ; Halasz, Ivan ; Užarević, Krunoslav ; Juribašić Kulcsar, Marina ; Ćurić, Manda

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Solid-State Science & Research : Book of Abstracts and Programme / Juribašić Kulcsar, Marina ; Halasz, Ivan - Zagreb : Institut Ruđer Bošković, 2017, 62-62

ISBN
978-953-7941-15-4

Skup
Solid-State Science & Research Meeting

Mjesto i datum
Zagreb, Hrvatska, 28.06.2017. - 30.06.2017

Vrsta sudjelovanja
Poster

Vrsta recenzije
Domaća recenzija

Ključne riječi
cyclopalladation ; mechanochemistry ; azobenzene ; acetate

Sažetak
During the last decades mechanochemical reactions have been established as a viable green-chemistry alternative to conventional solution chemistry and have thus far been employed for the synthesis of a large variety of compounds along with transition-metal catalysed C–H bond functionalization. Herein, we demonstrate the solid-state synthesis of azobenzene ligand and its dicyclopalladated complex via C-H bond activation by palladium(II) acetate, Pd(OAc)2, applying different mechanochemical methods. The direct insight into the reaction dynamics and formation mechanism of dicyclopalladated complex in the solid state have been studied by in situ and ex situ monitoring using Raman and NMR spectroscopies, respectively.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

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