Pregled bibliografske jedinice broj: 869938
Synthesis of a new T-shaped heterobinuclear Pt0-AuI complex [(t-Bu3P)2PtAu(PPh3)]BF4 from trinuclear gold cluster complex [(PPh3)Au]3(mu-O)BF4
Synthesis of a new T-shaped heterobinuclear Pt0-AuI complex [(t-Bu3P)2PtAu(PPh3)]BF4 from trinuclear gold cluster complex [(PPh3)Au]3(mu-O)BF4 // Scientia iranica, 23 (2016), 3; 1089-1094 doi:10.24200/sci.2016.3878 (međunarodna recenzija, članak, znanstveni)
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Naslov
Synthesis of a new T-shaped heterobinuclear Pt0-AuI complex [(t-Bu3P)2PtAu(PPh3)]BF4 from trinuclear gold cluster complex [(PPh3)Au]3(mu-O)BF4
Autori
Jamali, Sirous ; Ashtiani, Mona Maleka ; Milić, Dalibor
Izvornik
Scientia iranica (1026-3098) 23
(2016), 3;
1089-1094
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Synthesis ; Metal ; Complex ; Platinum ; Gold ; Cluster ; Binuclear
Sažetak
The heterobinuclear platinum(0)-gold(I) complex [(t-Bu3P)2PtAu(PPh3)] BF4, 5, was synthesized by the reaction of trinuclear cluster complex {; ; [(PPh3)Au]3(mu- O)}; ; BF4, 4, with one equiv of [(t-Bu3P)2Pt] at room temperature. The heterobinuclear complex 5 was characterized using multinuclear NMR spectroscopy and elemental microanalysis and was further identified by single crystal X-ray structure determination. Crystal structure of 5 shows a T-shaped geometry with an unsupported short distance Pt-Au dative bond.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Poveznice na cjeloviti tekst rada:
Pristup cjelovitom tekstu rada doi scientiairanica.sharif.edu scientiairanica.sharif.eduCitiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
