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Pregled bibliografske jedinice broj: 863402

A conductivity study of dilute aqueous solutions of tetramethylammonium hexacyanoferrate(III), tetraethylammonium hexacyanoferrate(III) and benzyltrimethylammonium hexacyanoferrate(III)

Pilepić, Viktor; Apelblat, Alexander; Bešter-Rogač, Marija
A conductivity study of dilute aqueous solutions of tetramethylammonium hexacyanoferrate(III), tetraethylammonium hexacyanoferrate(III) and benzyltrimethylammonium hexacyanoferrate(III) // Journal of molecular liquids, 228 (2017), 38-44 doi:10.1016/j.molliq.2016.08.077 (međunarodna recenzija, članak, znanstveni)

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Naslov
A conductivity study of dilute aqueous solutions of tetramethylammonium hexacyanoferrate(III), tetraethylammonium hexacyanoferrate(III) and benzyltrimethylammonium hexacyanoferrate(III)

Autori
Pilepić, Viktor ; Apelblat, Alexander ; Bešter-Rogač, Marija

Izvornik
Journal of molecular liquids (0167-7322) 228 (2017); 38-44

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Electrolyte conductivity ; Tetramethylammonium hexacyanoferrate(III) ; Tetraethylammonium hexacyanoferrate(III) ; Benzyltrimethylammonium hexacyanoferrate(III) ; Aqueous solutions ; Limiting ion conductances ; Formation constants

Sažetak
Electrical conductivities of tetramethylammonium hexacyanoferrate(III), tetraethylammonium hexacyanoferrate(III) and benzyltrimethylammonium hexacyanoferrate(III) in dilute aqueous solutions, in the 278.15 K to 313.15 K temperature range are reported. These conductivities are examined in terms of the molecular model which includes an existence of three ion species in the solution, the principal cation and anion and the additional anion formed by the association between them. Based on this molecular model, the representation of conductances was performed using the Quint-Viallard conductivity equation and the Debye-Hückel expression for activity coefficients. The thermodynamic of ion pair formation is discussed in terms of ion-solvent interactions.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Ustanove:
Farmaceutsko-biokemijski fakultet, Zagreb

Profili:

Avatar Url Viktor Pilepić (autor)

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com dx.doi.org

Citiraj ovu publikaciju:

Pilepić, Viktor; Apelblat, Alexander; Bešter-Rogač, Marija
A conductivity study of dilute aqueous solutions of tetramethylammonium hexacyanoferrate(III), tetraethylammonium hexacyanoferrate(III) and benzyltrimethylammonium hexacyanoferrate(III) // Journal of molecular liquids, 228 (2017), 38-44 doi:10.1016/j.molliq.2016.08.077 (međunarodna recenzija, članak, znanstveni)
Pilepić, V., Apelblat, A. & Bešter-Rogač, M. (2017) A conductivity study of dilute aqueous solutions of tetramethylammonium hexacyanoferrate(III), tetraethylammonium hexacyanoferrate(III) and benzyltrimethylammonium hexacyanoferrate(III). Journal of molecular liquids, 228, 38-44 doi:10.1016/j.molliq.2016.08.077.
@article{article, author = {Pilepi\'{c}, Viktor and Apelblat, Alexander and Be\v{s}ter-Roga\v{c}, Marija}, year = {2017}, pages = {38-44}, DOI = {10.1016/j.molliq.2016.08.077}, keywords = {Electrolyte conductivity, Tetramethylammonium hexacyanoferrate(III), Tetraethylammonium hexacyanoferrate(III), Benzyltrimethylammonium hexacyanoferrate(III), Aqueous solutions, Limiting ion conductances, Formation constants}, journal = {Journal of molecular liquids}, doi = {10.1016/j.molliq.2016.08.077}, volume = {228}, issn = {0167-7322}, title = {A conductivity study of dilute aqueous solutions of tetramethylammonium hexacyanoferrate(III), tetraethylammonium hexacyanoferrate(III) and benzyltrimethylammonium hexacyanoferrate(III)}, keyword = {Electrolyte conductivity, Tetramethylammonium hexacyanoferrate(III), Tetraethylammonium hexacyanoferrate(III), Benzyltrimethylammonium hexacyanoferrate(III), Aqueous solutions, Limiting ion conductances, Formation constants} }
@article{article, author = {Pilepi\'{c}, Viktor and Apelblat, Alexander and Be\v{s}ter-Roga\v{c}, Marija}, year = {2017}, pages = {38-44}, DOI = {10.1016/j.molliq.2016.08.077}, keywords = {Electrolyte conductivity, Tetramethylammonium hexacyanoferrate(III), Tetraethylammonium hexacyanoferrate(III), Benzyltrimethylammonium hexacyanoferrate(III), Aqueous solutions, Limiting ion conductances, Formation constants}, journal = {Journal of molecular liquids}, doi = {10.1016/j.molliq.2016.08.077}, volume = {228}, issn = {0167-7322}, title = {A conductivity study of dilute aqueous solutions of tetramethylammonium hexacyanoferrate(III), tetraethylammonium hexacyanoferrate(III) and benzyltrimethylammonium hexacyanoferrate(III)}, keyword = {Electrolyte conductivity, Tetramethylammonium hexacyanoferrate(III), Tetraethylammonium hexacyanoferrate(III), Benzyltrimethylammonium hexacyanoferrate(III), Aqueous solutions, Limiting ion conductances, Formation constants} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus

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