Pregled bibliografske jedinice broj: 862901
Electrochemical study of uranium(VI) in a queous solution of Tri-n-Butyl phosphate
Electrochemical study of uranium(VI) in a queous solution of Tri-n-Butyl phosphate // Journal of electroanalytical chemistry and interfacial electrochemistry, 33 (1971), 1; 61-68 doi:10.1016/S0022-0728(71)80208-5 (međunarodna recenzija, članak, znanstveni)
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Naslov
Electrochemical study of uranium(VI) in a queous
solution of Tri-n-Butyl phosphate
Autori
Krznarić, Damir ; Ćosović, Božena ; Branica, Marko
Izvornik
Journal of electroanalytical chemistry and interfacial electrochemistry (0022-0728) 33
(1971), 1;
61-68
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
uranium(vi) ; electrochemistry ; tri-n-butyl phosphate ; TBP
Sažetak
The adsorption of TBP at the mercury electrode was investigated by drop time and tensammetric measurements. The adsorption occurs in the potential range from approximately 0 V up to -1.3 V vs. SCE. The interaction of uranyl ion and TBP in aqueous solutions and in the adsorbed layer on Hg electrode surface was examined by polarography. In the presence of TBP the reduction wave of uranium(VI) splits into a reversible wave at -0.17 V and an irreversible one at -0.3 V. A bridge mechanism of electron transfer at the surface covered with TBP is suggested.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
