Pregled bibliografske jedinice broj: 849168
Aromatic C-Nitroso Compounds and their Dimers: A Model for Probing the Reaction Mechanisms in Crystalline Molecular Solids
Aromatic C-Nitroso Compounds and their Dimers: A Model for Probing the Reaction Mechanisms in Crystalline Molecular Solids // Crystals, 7 (2017), 12; 376, 15 doi:10.3390/cryst7120376 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 849168 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Aromatic C-Nitroso Compounds and their Dimers: A Model for Probing the Reaction Mechanisms in Crystalline Molecular Solids
Autori
Biljan, Ivana ; Vančik, Hrvoj
Izvornik
Crystals (2073-4352) 7
(2017), 12;
376, 15
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
C-nitroso compounds ; Solid-state reaction mechanisms ; Azodioxides
Sažetak
This review is focused on the dimerization and dissociation of aromatic C-nitroso compounds and their dimers, the reactions that could be used as a convenient model for studying the thermal organic solid-state reaction mechanisms. This molecular model is simple because it includes formation or breaking of only one covalent bond between two nitrogen atoms. The crystalline molecular solids of nitroso dimers (azodioxides) dissociate by photolysis under the cryogenic conditions, and re-dimerize by slow warming. The thermal re-dimerization reaction is examined under the different topotactic conditions in crystals: disordering, surface defects, and phase transformations. Depending on the conditions, and on the molecular structure, aromatic C-nitroso compounds can associate to form one-dimensional polymeric structures and are able to self-assembly on gold surface.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
HRZZ-IP-2013-11-7444 - Organske molekule u kondenziranoj fazi: međudjelovanja i modeliranje (ORGMOL) (Vančik, Hrvoj, HRZZ - 2013-11) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
