Naslov
Effect of acidity and texture of micro-, mesoporous, and hybrid micromesoporous materials on the synthesis of paramenthanic diol exhibiting anti-Parkinson activity

Autori
A. Torozova, P. Mäki-Arvela, N. D. Shcherban, N. Kumar, A. Aho, M. Stekrova, K. Maduna Valkaj, P. Sinitsyna, S. M. Filonenko, P. S. Yaremov, V. G. Ilyin, K. P. Volcho, N. F. Salakhutdinov, D. Yu. Murzin

Izvornik
Catalysis, structure & reactivity (2055-0758) 1 (2015); 146-154

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Zeolites ; Hybrid micro-mesoporous materials ; MCM-41 ; MCM-48 ; Beta zeolites ; Verbenol oxide isomerization

Sažetak
Microporous, mesoporous, and new hybrid materials were studied in verbenol oxide isomerization for the synthesis of biologically active substance with anti- Parkinson activity. H-Si-MCM-41, H-Al- MCM-41, H- Al- MCM-48, H-Beta-25, and H-Beta-300 were compared with hybrid materials. The latter with a zeolite-like micromesoporous structure were characterized and evaluated for their catalytic activity for the first time. The approach of dual templating for synthesis of new materials was applied in this work to combine properties of Beta-zeolites and mesoporous cellular foams (MCF). The selectivity to the target product was the highest over microporous mild acidic H-Beta- 300 and hybrid ZF-100, with also mild acidity and even absence of strong acid sites. Selectivity at 97 and 99% of conversion was 61 and 59% for H-Beta-300 and hybrid ZF-100, respectively.

Izvorni jezik
Engleski

Znanstvena područja
Kemijsko inženjerstvo, Interdisciplinarne tehničke znanosti

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