Pregled bibliografske jedinice broj: 830226
ESI-MS studies of the non-covalent interactions between biologically important metal ions and N- sulfonylcytosine derivatives
ESI-MS studies of the non-covalent interactions between biologically important metal ions and N- sulfonylcytosine derivatives // Journal of mass spectrometry, 51 (2016), 11; 998-1005 doi:10.1002/jms.3810 (međunarodna recenzija, članak, znanstveni)
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Naslov
ESI-MS studies of the non-covalent interactions between biologically important metal ions and N- sulfonylcytosine derivatives
Autori
Ključarić, Valentina ; Kobetić, Renata ; Rinkovec, Jasmina ; Kazazić, Snježana ; Gembarovski, Dubravka ; Saftić, Dijana ; Matić, Josipa ; Ban, Željka ; Žinić, Biserka
Izvornik
Journal of mass spectrometry (1076-5174) 51
(2016), 11;
998-1005
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
N-1-sulfonylcytosine derivatives ; Cu(II) complexes ; metal ions Na+ ; K+ ; Ca2+ ; Mg2+ ; Zn2+ ; non-covalent interactions ; ESI-MS
Sažetak
The aim of this report is to present the electrospray ionization (ESI-MS) results of the non-covalent interaction of two biologically active ligands, N-1-(p-toluenesulfonyl)cytosine, 1-TsC, 1 and N-1-methanesulfonylcytosine, 1-MsC, 2 and their Cu(II) complexes Cu(1-TsC-N3)2Cl2, 3 and Cu(1-MsC-N3)2Cl2, 4 with biologically important cations: Na+, K+, Ca2+, Mg2+ and Zn2+. The formation of various complex metal ions was observed. The alkali metals Na+ and K+ formed clusters due to electrostatic interactions. Ca2+ and Mg2+ salts produced the tris ligand and mixed ligand complexes. The interaction of Zn2+ with 1-4 produced monometal and dimetal Zn2+ complexes as a result of the affinity of Zn2+ ions towards both O and N atoms.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
HRZZ-IP-2013-11-1477 - Višenamjensko očitavanje DNA/RNA sekundarne strukture molekularnim kemijskim senzorima (DNA/RNA-MolSense) (Piantanida, Ivo, HRZZ - 2013-11) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Profili:
Dubravka Gembarovski
(autor)
Željka Ban
(autor)
Josipa Matić
(autor)
Dijana Pavlović Saftić
(autor)
Biserka Žinić
(autor)
Jasmina Rinkovec
(autor)
Renata Kobetić
(autor)
Snježana Kazazić
(autor)
Valentina Ključarić
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE