Pregled bibliografske jedinice broj: 807859
Metal nanoparticles deposited on porous silicon templates as novel substrates for SERS
Metal nanoparticles deposited on porous silicon templates as novel substrates for SERS // Croatica chemica acta, 88 (2015), 4; 437-444 doi:10.5562/cca2769 (međunarodna recenzija, članak, znanstveni)
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Naslov
Metal nanoparticles deposited on porous silicon
templates as novel substrates for SERS
Autori
Mikac, Lara ; Ivanda, Mile ; Gotić, Marijan ; Maksimović, Aleksandar ; Trusso, Sebastiano ; D’Andrea, Cristiano ; Foti, Antonino ; Irrera, Alessia ; Fazio, Barbara ; Gucciardi, Pietro Giuseppe
Izvornik
Croatica chemica acta (0011-1643) 88
(2015), 4;
437-444
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
macroporous silicon ; SERS ; substrate ; laser ablation
Sažetak
In this paper, results on preparation of stable and uniform SERS solid substrates using macroporous silicon (pSi) with deposited silver and gold are presented. Macroporous silicon is produced by anodisation of p-type silicon in hydrofluoric acid. The as prepared pSi is then used as a template for Ag and Au depositions. The noble metals were deposited in three different ways: by immersion in silver nitrate solution, by drop-casting silver colloidal solution and by pulsed laser ablation (PLA). Substrates obtained by different deposition processes were evaluated for SERS efficiency using methylene blue (MB) and rhodamine 6G (R6G) at 514.5, 633 and 785 nm. Using 514.5 nm excitation and R6G the limits of detection (LOD) for macroporous Si samples with noble metal nanostructures obtained by immersion of pSi sample in silver nitrate solution and by applying silver colloidal solution to pSi template were 10–9 M and 10–8 M respectively. Using 633 nm laser and MB the most noticeable SERS activity gave pSi samples ablated with 30000 and 45000 laser pulses where the LODs of 10–10 M were obtained. The detection limit of 10–10 M was also reached for 4 mA cm–2-15 min pSi sample, silver ablated with 30000 pulses. Macroporous silicon proved to be a good base for the preparation of SERS substrates.
Izvorni jezik
Engleski
Znanstvena područja
Fizika, Kemija
POVEZANOST RADA
Projekti:
HRZZ-IP-2014-09-7046 - Hibridne silicijske nanstrukture za senzorik (NANOSENS) (Ivanda, Mile, HRZZ - 2014-09) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus