Pregled bibliografske jedinice broj: 807298
Role of the ‘weakest link’ in a pressure-driven phase transition of two polytypic polymorphs
Role of the ‘weakest link’ in a pressure-driven phase transition of two polytypic polymorphs // Crystal growth & design, 16 (2016), 4; 2040-2051 doi:10.1021/acs.cgd.5b01690 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 807298 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Role of the ‘weakest link’ in a pressure-driven phase transition of two polytypic polymorphs
Autori
Kodrin, Ivan ; Soldin, Željka ; Aakeroy, Christer B. ; Đaković, Marijana
Izvornik
Crystal growth & design (1528-7483) 16
(2016), 4;
2040-2051
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
pressure induced polymorphism ; polytypism ; cadmium(II) complexes
Sažetak
A detailed comparison of two polytypic polymorphs of bis-(2-aminopyrazine) di- iodocadmium(II), using a combination of theory and experiment, reveals how the relative stabilities of the two forms can be linked in a very precise manner to subtle differences in intermolecular interactions in the two structures. A versatile and practical workflow for examining closely related polymorphs is presented, and physical properties of the two forms are rationalized against the details of the structural landscape that evolved during this investigation. The possible role of relatively weak hydrogen-bond interactions for promoting and facilitating polymorphic behavior in coordination complexes in general is examined further using theory and data mining.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
HRZZ-UIP-2013-11-1809 - Inženjering kristalnih materijala pomoću metalnih kompleksa i nekovalentnih interakcija (CRYSTIN) (Đaković, Marijana, HRZZ - 2013-11) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
