Pregled bibliografske jedinice broj: 802400
In situ monitoring and mechanism of the mechanochemical formation of a microporous MOF-74 framework
In situ monitoring and mechanism of the mechanochemical formation of a microporous MOF-74 framework // Journal of the American Chemical Society, 138 (2016), 9; 2929-2932 doi:10.1021/jacs.5b13038 (međunarodna recenzija, članak, znanstveni)
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Naslov
In situ monitoring and mechanism of the mechanochemical formation of a microporous MOF-74 framework
Autori
Julien, Patrick A. ; Užarević, Krunoslav ; Katsenis, Athanassios D. ; Kimber, Simon A.J. ; Wang, Timothy ; Farha, Omar K. ; Zhang, Yuancheng ; Casaban, José ; Germann, Luzia ; Etter, Martin ; Dinnebier, Robert E. ; James, Stuart L. ; Halasz, Ivan ; Friščić, Tomislav
Izvornik
Journal of the American Chemical Society (0002-7863) 138
(2016), 9;
2929-2932
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
mechanochemistry ; in situ monitoring ; X-ray diffraction ; mechanism ; MOF-74 ; metal-organic framework
Sažetak
Mechanochemistry provides a rapid, efficient route to metal-organic framework Zn-MOF-74 directly from a metal oxide and without bulk solvent. In situ synchrotron X-ray diffraction monitoring of the reaction course reveals two new phases and an unusual step-wise process in which a close-packed intermediate reacts to form the open framework. The reaction can be performed on a gram scale to yield a highly porous material after activation.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- Arts & Humanities Citation Index (A&HCI)
- SCI-EXP, SSCI i/ili A&HCI
- Nature Index