Pregled bibliografske jedinice broj: 789969
Mechanochemical and Solvent-free Assembly of Zirconium-Based Metal-organic Frameworks
Mechanochemical and Solvent-free Assembly of Zirconium-Based Metal-organic Frameworks // Chemical communications, 52 (2016), 2133-2136 doi:10.1039/c5cc08972g (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 789969 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Mechanochemical and Solvent-free Assembly of Zirconium-Based Metal-organic Frameworks
Autori
Užarević, Krunoslav ; Wang, Timothy C. ; Moon, Su-Young ; Fidelli, Athena M. ; Hupp, Joseph T. ; Farha, Omar K. ; Friščić, Tomislav
Izvornik
Chemical communications (1359-7345) 52
(2016);
2133-2136
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
mechanochemical synthesis; microporous metal-organic materials; catalysis; warfare destruction
Sažetak
We develop the first mechanochemical and solvent-free routes for zirconium metal-organic frameworks, making the frameworks UiO-66 and UiO-66-NH2 accessible on gram scale without strong acid, high temperature or excess reactants. The frameworks form either by milling or spontaneously self-assemble by simply exposing solid mixtures of reactants to organic vapour. Generated frameworks exhibit high porosity and catalytic activity in hydrolysis of model nerve agents, on par with solvothermally generated counterparts.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Napomena
Rad je nastao uz financiranje KU od strane FP7- PEOPLE-2011-COFUND program NEWFELPRO, broj ugovora 62.
POVEZANOST RADA
Projekti:
FP7-NEWFELPRO-62
Ustanove:
Institut "Ruđer Bošković", Zagreb
Profili:
Krunoslav Užarević
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- Arts & Humanities Citation Index (A&HCI)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
- Nature Index