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Pregled bibliografske jedinice broj: 778402

Synthesis, characterization and catalytic studies od a new two-dimensiional metal-organic framework based on Co-carboxylate secondary building units

Bagherzadeh, Mojtaba; Ashouri, Fatemeh; Đaković, Marijana
Synthesis, characterization and catalytic studies od a new two-dimensiional metal-organic framework based on Co-carboxylate secondary building units // Journal of solid state chemistry, 223 (2015), SI; 32-37 doi:10.1016/j.jssc.2014.05.011 (međunarodna recenzija, članak, znanstveni)

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Naslov
Synthesis, characterization and catalytic studies od a new two-dimensiional metal-organic framework based on Co-carboxylate secondary building units

Autori
Bagherzadeh, Mojtaba ; Ashouri, Fatemeh ; Đaković, Marijana

Izvornik
Journal of solid state chemistry (0022-4596) 223 (2015), SI; 32-37

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
two-dimensional polymer ; metal-organic framework ; cobalt complex ; olefin oxidation ; heterogeneous catalyst

Sažetak
A metal-organic framework [Co3(BDC)3(DMF)2(H2O)2] was synthesised and structarally characterized. Y-ray single crystal analysis revealed that the framework contains a 2D polymeric chain through coordination of 1, 4-benzenedicarboxylic acid linker ligand to cobalt center. The polymer crystallize in monoclinic P21/c space group with a=13.989(3)A, b=9.6728(17)A, c=16.707(3)A, Z=2. The polymer features a framework based on the perfect octahedral Co-O6 secondary building units. The catalytical acivities of [Co3(BDC)3(DMF)2(H2O)2]n for olefines oxidation was conducted. The heterogeneous catalyst could be facilely separated from the reaction mixture, and reused three times without significant degradation in catalytic activity. Furthermore, no contribution from homogeneous catalysis of active species leaching into reaction solution was detected.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Projekti:
119-1193079-1332 - Kemija metalnih kompleksa u reakcijama od biološkog značaja i novim materijalima (Popović, Zora, MZOS ) ( CroRIS)

Ustanove:
Prirodoslovno-matematički fakultet, Zagreb

Profili:

Avatar Url Marijana Đaković (autor)

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com

Citiraj ovu publikaciju:

Bagherzadeh, Mojtaba; Ashouri, Fatemeh; Đaković, Marijana
Synthesis, characterization and catalytic studies od a new two-dimensiional metal-organic framework based on Co-carboxylate secondary building units // Journal of solid state chemistry, 223 (2015), SI; 32-37 doi:10.1016/j.jssc.2014.05.011 (međunarodna recenzija, članak, znanstveni)
Bagherzadeh, M., Ashouri, F. & Đaković, M. (2015) Synthesis, characterization and catalytic studies od a new two-dimensiional metal-organic framework based on Co-carboxylate secondary building units. Journal of solid state chemistry, 223 (SI), 32-37 doi:10.1016/j.jssc.2014.05.011.
@article{article, author = {Bagherzadeh, Mojtaba and Ashouri, Fatemeh and \DJakovi\'{c}, Marijana}, year = {2015}, pages = {32-37}, DOI = {10.1016/j.jssc.2014.05.011}, keywords = {two-dimensional polymer, metal-organic framework, cobalt complex, olefin oxidation, heterogeneous catalyst}, journal = {Journal of solid state chemistry}, doi = {10.1016/j.jssc.2014.05.011}, volume = {223}, number = {SI}, issn = {0022-4596}, title = {Synthesis, characterization and catalytic studies od a new two-dimensiional metal-organic framework based on Co-carboxylate secondary building units}, keyword = {two-dimensional polymer, metal-organic framework, cobalt complex, olefin oxidation, heterogeneous catalyst} }
@article{article, author = {Bagherzadeh, Mojtaba and Ashouri, Fatemeh and \DJakovi\'{c}, Marijana}, year = {2015}, pages = {32-37}, DOI = {10.1016/j.jssc.2014.05.011}, keywords = {two-dimensional polymer, metal-organic framework, cobalt complex, olefin oxidation, heterogeneous catalyst}, journal = {Journal of solid state chemistry}, doi = {10.1016/j.jssc.2014.05.011}, volume = {223}, number = {SI}, issn = {0022-4596}, title = {Synthesis, characterization and catalytic studies od a new two-dimensiional metal-organic framework based on Co-carboxylate secondary building units}, keyword = {two-dimensional polymer, metal-organic framework, cobalt complex, olefin oxidation, heterogeneous catalyst} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus

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