Pregled bibliografske jedinice broj: 725655
Molecular recognition of Ca2+ cations by internal and external receptors/interfaces in a spherical porous molybdenum-oxide capsule: unusual coordination scenarios
Molecular recognition of Ca2+ cations by internal and external receptors/interfaces in a spherical porous molybdenum-oxide capsule: unusual coordination scenarios // Inorganic chemistry frontiers, 1 (2014), 740-744 doi:10.1039/C4QI00131A (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 725655 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Molecular recognition of Ca2+ cations by
internal and external receptors/interfaces in a
spherical porous molybdenum-oxide capsule:
unusual coordination scenarios
Autori
Rubčić, Mirta ; Korenev, Vladimir S. ; Toma, Liviu ; Bögge, Hartmut ; Fedin, Vladimir P. ; Müller, Achim
Izvornik
Inorganic chemistry frontiers (2052-1545) 1
(2014);
740-744
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
molybdenum-oxide capsule ; molecular recognition ; Ca cations ; water assembly
Sažetak
The unique molybdenum-oxide capsule [{; ; ; ; ; (MoVI)MoVI 5O21(H2O)6}; ; ; ; ; 12{; ; ; ; ; MoV 2O4(SO4)}; ; ; ; ; 30]72− shows an unprecedented affinity towards Ca2+ cations which interact in fully or partially hydrated forms with different well- defined internal and external receptor areas via direct coordination and/or hydrogen bonds. The cavity of the capsule comprises an unusual “water assembly” of the Ca20{; ; ; ; ; H2O}; ; ; ; ; 60=Ca20{; ; ; ; ; (H2O)5}; ; ; ; ; 12 type. Altogether, we can refer to a unique solid-state structure.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
MZOS-119-1191342-1082 - Novi kompleksni spojevi i materijali-kemijski i biološki katalizatori (Cindrić, Marina, MZOS ) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Profili:
Mirta Rubčić
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
