Pregled bibliografske jedinice broj: 711354
Inorganic Spherical Cells: Versatile Platforms for New Phenomena at the Nanoscale
Inorganic Spherical Cells: Versatile Platforms for New Phenomena at the Nanoscale // 3rd FMOCS – PoCheMoN Frontiers in Metal-Oxide Cluster Science Symposium & European conference “Polyoxometalate Chemistry for Molecular Nanoscience” / Proust, Anna ; Izzet, Guillaume ; Villanneau, Richard ; Dolbecq, Anne ; Lacôte, Emmanuel (ur.).
Pariz, 2014. str. P11-P11 (poster, nije recenziran, sažetak, znanstveni)
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Naslov
Inorganic Spherical Cells: Versatile Platforms for
New Phenomena at the Nanoscale
Autori
Garai, Somenath ; El Moll, Hani ; Rubčić, Mirta ; Merca, Alice ; Bögge, Hartmut ; Müller, Achim
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
3rd FMOCS – PoCheMoN Frontiers in Metal-Oxide Cluster Science Symposium & European conference “Polyoxometalate Chemistry for Molecular Nanoscience”
/ Proust, Anna ; Izzet, Guillaume ; Villanneau, Richard ; Dolbecq, Anne ; Lacôte, Emmanuel - Pariz, 2014, P11-P11
Skup
3rd FMOCS – PoCheMoN Frontiers in Metal-Oxide Cluster Science Symposium & European conference “Polyoxometalate Chemistry for Molecular Nanoscience”
Mjesto i datum
Maffliers, Francuska, 12.07.2014. - 15.07.2014
Vrsta sudjelovanja
Poster
Vrsta recenzije
Nije recenziran
Ključne riječi
Polyoxometalates ; Keplerates
Sažetak
The unique spherical nanocapsules/Keplerates of the type {; ; ; ; ; {; ; ; ; ; (Mo)Mo5}; ; ; ; ; 12M’30 (M’ = {; ; ; ; ; MoV2}; ; ; ; ; , VIV, CrIII, FeIII) (more generally: (pentagon)12(spacer/ligand)30) allow – due to their exceptional structural features and easy variations/derivatizations – versatile chemistry and applications as well as the option to study new phenomena of interdisciplinary interest. In this poster we specially refer on the interesting neutral/charged species of [{; ; ; ; ; (MoVI)MoVI 5O21(L)6}; ; ; ; ; 12{; ; ; ; ; FeIII(H2O)L}; ; ; ; ; 30] (L = H2O/CH3COO- /Mo2O8/9 n-) 1a/type not only because of their tremendous unusual magnetic properties which exhibit spherical networks based on corner- shared M’3 triangles causing geometrical frustration analogous to that of the planar Kagomé lattices but also for their behavior as unique weak polyprotic acids owing to the external water ligands attached to the M’ metal centers. In the second part we refer to the fact that the capsule [{; ; ; ; ; (MoVI)MoVI 5O21(H2O)6}; ; ; ; ; 12{; ; ; ; ; MoV 2O4(CO3)}; ; ; ; ; 30]72- 2a containing 30 carbonate ligands is a potential starting reagent for the synthesis of novel capsules with weakly coordination ligands such as fluoride ions [{; ; ; ; ; (MoVI)MoVI5O21(H2O)5F}; ; ; ; ; 12 {; ; ; ; ; MoV2O4(F)(H2O)}; ; ; ; ; 30]69- 3a.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
