Pregled bibliografske jedinice broj: 710823
A Series of Molybdenum(VI) Complexes with Tridentate Schiff Base Ligand
A Series of Molybdenum(VI) Complexes with Tridentate Schiff Base Ligand // Zeitschrift für anorganische und allgemeine Chemie, 628 (2002), 9/10; 2113-2117 doi:10.1002/1521-3749(200209)628:9 (međunarodna recenzija, članak, znanstveni)
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Naslov
A Series of Molybdenum(VI) Complexes with Tridentate Schiff Base Ligand
Autori
Cindrić, Marina ; Strukan, Neven ; Vrdoljak, Višnja ; Kajfež, Tanja ; Kamenar, Boris
Izvornik
Zeitschrift für anorganische und allgemeine Chemie (0044-2313) 628
(2002), 9/10;
2113-2117
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
molybdenum; Schiff base; tridentate ligands; crystal structure
Sažetak
Mononuclear and polynuclear dioxomolybdenum(VI) complexes with Schiff base ligands have been prepared by the reaction of [MoO2(acac)2] with salicylaldehyde (1 and 4), 2-hydroxy-1-naphthaldehyde (2 and 5) and 2-hydroxy-3-methoxybenzaldehyde (3 and 6) with addition of appropriate amine. All prepared complexes of the general formulae [MoO2LD] and [MoO2L]n consist of cis-MoO22+ core coordinated by Schiff-base ligand (L) in a tridentate manner through two deprotonated hydroxyl groups and one imino nitrogen. The usual octahedral coordination around molybdenum atom is completed by monodentate solvent molecules D (methanol, ethanol or dimethylsulphoxide). All compounds were characterized by means of chemical analysis, IR spectroscopy, thermogravimetric analysis and some of them by X-ray crystallography (1a, 2c, 3a, 4c and 6c).
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
