Pregled bibliografske jedinice broj: 69374
SPECTROSCOPIC ANALYSIS OF trans-9-(4-CYANOSTYRYL)-2,3,6,7-TETRAHYDRO-1H,5H-PYRIDO[3,2,1-i,j]-QUINOLINE AND ITS DEUTERIUM LABELLED ISOTOPOMERS
SPECTROSCOPIC ANALYSIS OF trans-9-(4-CYANOSTYRYL)-2,3,6,7-TETRAHYDRO-1H,5H-PYRIDO[3,2,1-i,j]-QUINOLINE AND ITS DEUTERIUM LABELLED ISOTOPOMERS // Book of Abstracts / Rui, Fausto ; Digo, Elsa (ur.).
Coimbra: Universidade de Coimbra, 2000. (poster, međunarodna recenzija, sažetak, znanstveni)
CROSBI ID: 69374 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
SPECTROSCOPIC ANALYSIS OF trans-9-(4-CYANOSTYRYL)-2,3,6,7-TETRAHYDRO-1H,5H-PYRIDO[3,2,1-i,j]-QUINOLINE AND ITS DEUTERIUM LABELLED ISOTOPOMERS
Autori
Smrečki, Vilko ; Novak, Predrag ; Lukić, Igor ; Meić, Zlatko
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
Book of Abstracts
/ Rui, Fausto ; Digo, Elsa - Coimbra : Universidade de Coimbra, 2000
Skup
25th European Congress on Molecular Spectroscopy (EUCMOS XXV)
Mjesto i datum
Coimbra, Portugal, 27.08.2000. - 01.09.2000
Vrsta sudjelovanja
Poster
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
spectroscopic analysis; isotopomers; NMR; julolidine
Sažetak
Stilbene derivative trans-9-(4-cyanostyryl)-2,3,6,7-tetrahydro-1H,5H-pyrido-[3,2,1-i,j]-quinoline (julolidine stilbene, JSB) and its three deuterium labelled isotopomers were prepared by the Wittig-Horner-Emmons method. Their 1H and 13C NMR, infrared, Raman and mass spectra were recorded and assigned. Reaction mechanism and problems that occurred during the synthesis of a series of deuterium labelled isotopomers were followed by a combined spectroscopic analysis. For example, in order to aviod exchange of deuterium with hydrogen in the olefinic bridge, deuterium labelled solvents should be used. Th emost important results relevant to push-pull stilbenes will be discussed.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb
