Pregled bibliografske jedinice broj: 687933
Theory of kinetically controlled electrode reaction coupled to ion transfer across the liquid / liquid interface
Theory of kinetically controlled electrode reaction coupled to ion transfer across the liquid / liquid interface // ChemElectroChem, 1 (2014), 2; 436-440 doi:10.1002/celc.201300048 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 687933 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Theory of kinetically controlled electrode
reaction coupled to ion transfer across the
liquid / liquid interface
Autori
Komorsky-Lovrić, Šebojka ; Lovrić, Milivoj
Izvornik
ChemElectroChem (2196-0216) 1
(2014), 2;
436-440
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Ion transfer ; liquid ; liquid interface ; kinetics of electrode reaction ; linear scan voltammetry
Sažetak
An electron transfer reaction at graphite electrode that is covered by a thin film of organic solvent, which is immiscible with water, and immersed into an aqueous electrolyte is considered theoretically. The redox couple is confined within the film and the conductivity is achieved by the transfer of anion of supporting electrolyte across the organic solvent / water interface. In linear scan voltammetry the peak potential depends on the initial concentration of either reactant, or the anion of supporting electrolyte in the film. A critical value of dimensionless kinetic parameter, which can be used for the determination of standard rate constant, is calculated.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
MZOS-098-0982904-2907 - Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci (Lovrić, Milivoj, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
