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Pregled bibliografske jedinice broj: 685215

Temperature-dependent IR spectroscopic and structural study of 18-crown-6 chelating ligand in the complexation with sodium surfactant salts

Mihelj, Tea; Tomašić, Vlasta; Biliškov, Nikola; Liu, Feng
Temperature-dependent IR spectroscopic and structural study of 18-crown-6 chelating ligand in the complexation with sodium surfactant salts // Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 124 (2014), 12-20 doi:10.1016/j.saa.2013.12.092 (međunarodna recenzija, članak, znanstveni)

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Naslov
Temperature-dependent IR spectroscopic and structural study of 18-crown-6 chelating ligand in the complexation with sodium surfactant salts

Autori
Mihelj, Tea ; Tomašić, Vlasta ; Biliškov, Nikola ; Liu, Feng

Izvornik
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy (1386-1425) 124 (2014); 12-20

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
18-crown-6 ether; IR spectroscopy; X-ray diffraction; anionic surfactants; thermal properties; liquid crystals

Sažetak
18-crown-6 ether (18C6) complexes with the following anionic surfactants: sodium n-dodecylsulfate (18C6-NaDS), sodium 4-(1-pentylheptyl)benzenesulfonate (18C6-NaDBS) ; and potassium picrate (18C6-KP) were synthesized and studied in terms of their thermal and structural properties. Physico-chemical properties of new solid 1:1 coordination complexes were characterized by infrared (IR) spectroscopy, thermogravimetry and differential thermal analysis, differential scanning calorimetry, X-ray diffraction and microscopic observations. The strength of coordination between Na+ and oxygen atoms of 18C6 ligand does not depend on anionic part of the surfactant, as established by thermodynamical parameters obtained by temperature-dependent IR spectroscopy. Each of these complexes exhibit different kinds of endothermic transitions in heating scan. Diffraction maxima obtained by SAXS and WAXS, refer the behavior of the compounds 18C6-NaDS and 18C6-NaDBS as smectic liquid crystalline. Distortion of 18C6-NaDS and 18C6-KP complexes occurs in two steps. Temperature of the decomplexation of solid crystal complex 18C6-KP is considerably higher than of mesophase complexes, 18C6-NaDS, and 18C6-NaDBS. The structural and liquid crystalline properties of novel 18-crown-ether complexes are function of anionic molecule geometry, type of chosen cation (Na+, K+), as well as architecture of self-organized aggregates. A good combination of crown ether unit and amphiphile may provide a possibility for preparing new functionalized materials, opening the research field of ion complexation and of host-guest type behavior.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Projekti:
098-0982904-2927 - Makrociklički ligandi, strukturne promjene otopina i molekularne spektroskopije (Baranović, Goran, MZOS ) ( CroRIS)
098-0982915-2949 - Površinski aktivne tvari, procesi u otopinama i na međupovršinama (Dutour Sikirić, Maja, MZOS ) ( CroRIS)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Tea Mihelj Josipović (autor)

Avatar Url Vlasta Tomašić (autor)

Avatar Url Nikola Biliškov (autor)

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com ac.els-cdn.com dx.doi.org

Citiraj ovu publikaciju:

Mihelj, Tea; Tomašić, Vlasta; Biliškov, Nikola; Liu, Feng
Temperature-dependent IR spectroscopic and structural study of 18-crown-6 chelating ligand in the complexation with sodium surfactant salts // Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 124 (2014), 12-20 doi:10.1016/j.saa.2013.12.092 (međunarodna recenzija, članak, znanstveni)
Mihelj, T., Tomašić, V., Biliškov, N. & Liu, F. (2014) Temperature-dependent IR spectroscopic and structural study of 18-crown-6 chelating ligand in the complexation with sodium surfactant salts. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 124, 12-20 doi:10.1016/j.saa.2013.12.092.
@article{article, author = {Mihelj, Tea and Toma\v{s}i\'{c}, Vlasta and Bili\v{s}kov, Nikola and Liu, Feng}, year = {2014}, pages = {12-20}, DOI = {10.1016/j.saa.2013.12.092}, keywords = {18-crown-6 ether, IR spectroscopy, X-ray diffraction, anionic surfactants, thermal properties, liquid crystals}, journal = {Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy}, doi = {10.1016/j.saa.2013.12.092}, volume = {124}, issn = {1386-1425}, title = {Temperature-dependent IR spectroscopic and structural study of 18-crown-6 chelating ligand in the complexation with sodium surfactant salts}, keyword = {18-crown-6 ether, IR spectroscopy, X-ray diffraction, anionic surfactants, thermal properties, liquid crystals} }
@article{article, author = {Mihelj, Tea and Toma\v{s}i\'{c}, Vlasta and Bili\v{s}kov, Nikola and Liu, Feng}, year = {2014}, pages = {12-20}, DOI = {10.1016/j.saa.2013.12.092}, keywords = {18-crown-6 ether, IR spectroscopy, X-ray diffraction, anionic surfactants, thermal properties, liquid crystals}, journal = {Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy}, doi = {10.1016/j.saa.2013.12.092}, volume = {124}, issn = {1386-1425}, title = {Temperature-dependent IR spectroscopic and structural study of 18-crown-6 chelating ligand in the complexation with sodium surfactant salts}, keyword = {18-crown-6 ether, IR spectroscopy, X-ray diffraction, anionic surfactants, thermal properties, liquid crystals} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus
  • MEDLINE

Uključenost u ostale bibliografske baze podataka::


  • Analytical Abstracts
  • INSPEC
  • Scopus

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