Pregled bibliografske jedinice broj: 620135
Theory of square-wave voltammogram starting at the equilibrium potential
Theory of square-wave voltammogram starting at the equilibrium potential // Journal of electroanalytical chemistry, 693 (2013), 56-59 doi:10.1016/j.jelechem.2013.01.029 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 620135 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Theory of square-wave voltammogram starting at the equilibrium potential
Autori
Jadreško, Dijana
Izvornik
Journal of electroanalytical chemistry (1572-6657) 693
(2013);
56-59
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
square-wave voltammetry; equilibrium potential; theory; redox state; Tafel plot
Sažetak
If both a reactant and product of an electrode reaction are present in the bulk of solution, the square-wave voltammogram can be recorded by starting at the equilibrium potential. If the reaction is reversible, the redox state of investigated substance can be estimated from the ratio of peak currents of the forward and backward components. The degree of reversibility of the reaction can be assessed from the current at the starting potential. Also, the dependence of the logarithm of forward component of irreversible response on the electrode potential can be used for the calculation of transfer coefficient.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982904-2907 - Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci (Lovrić, Milivoj, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Profili:
Dijana Jadreško
(autor)
Poveznice na cjeloviti tekst rada:
Pristup cjelovitom tekstu rada doi
www.sciencedirect.com
ac.els-cdn.com
dx.doi.org
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
