Naslov
Morphology, Microstructure, and Magnetic Properties of Ordered Large-Pore Mesoporous Cadmium Ferrite Thin Film Spin Glasses

Autori
Reitz, Christian ; Suchomski, Christian ; Sai Kiran Chakravadhanula, Venkata ; Djerdj, Igor ; Jagličić, Zvonko ; Brezesinski, Torsten

Izvornik
Inorganic chemistry (0020-1669) 52 (2013), 7; 3744-3754

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
ordered porous material; ferrite

Sažetak
Herein, we report the synthesis, microstructure, and magnetic properties of cadmium ferrite (CdFe2O4) thin films with both an ordered cubic network of 18 nm diameter pores and single-phase spinel grains averaging 13 nm in diameter. These mesoporous materials were produced through facile polymer templating of hydrated nitrate salt precursors. Both the morphology and microstructure, including cation site occupancy and electronic bonding configuration, were analyzed in detail by electron microscopy, grazing incidence small-angle X-ray scattering, Raman and X-ray photoelectron spectroscopy, and N2-physisorption. The obtained data demonstrate that the network of pores is retained up to annealing temperatures as high as 650 °C – the onset of crystallization is at ϑ = (590 ± 10) °C. Furthermore, they show that the polymer-templated samples exhibit a “partially” inverted spinel structure with inversion parameter λ = 0.40 ± 0.02. This differs from microcrystalline CdFe2O4 which shows virtually no inversion. Magnetic susceptibility studies reveal ferrimagnetic spin coupling below 147 K and further point to the likelihood of glassy behavior at low temperature (Tf ≈ 60 K). In addition, analysis of room temperature magnetization data indicates the presence of sub-10 nm diameter superparamagnetic clusters in an otherwise paramagnetic environment.

Izvorni jezik
Engleski

Znanstvena područja
Fizika

POVEZANOST RADA