Pregled bibliografske jedinice broj: 619004
V=O...C interactions in crystal structures of oxovanadium-coordination compounds
V=O...C interactions in crystal structures of oxovanadium-coordination compounds // New journal of chemistry, 37 (2013), 3; 619-623 doi:10.1039/C2NJ40780A (međunarodna recenzija, članak, znanstveni)
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Naslov
V=O...C interactions in crystal structures of oxovanadium-coordination compounds
Autori
Stilinović, Vladimir ; Bučar, Dejan-Krešimir ; Halasz, Ivan ; Meštrović, Ernest
Izvornik
New journal of chemistry (1144-0546) 37
(2013), 3;
619-623
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
intermolecular interactions; crystal engineering; oxovanadium
Sažetak
A survey of the Cambridge Structural Database (CSD) revealed the existence of a new supramolecular homosynthon in oxovanadium coordination compounds (OCCs) that is based on non-covalent V=O...C interactions. V=O...C close contacts were found in 38.7% of structures containing vanadyl or pervanadyl groups. The V=O...C interaction is clearly distinguishable from a putative V=O...H–C hydrogen bond upon analysis of OCC crystal structures deposited in the CSD. In the majority of structures, the OCCs assemble to form dimers or polymers. The V=O...C interactions were also found to lead to self-assembly of two new oxovanadium β-diketonate complexes into dimers in the solid state.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
119-1193079-3069 - Novi organski i koordinacijski spojevi - sinteza i suodnos struktura-svojstvo (Kaitner, Branko, MZOS ) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
