Pregled bibliografske jedinice broj: 609304
Empirical model for the stability constants of acetate mono-complexes with La3+, Nd3+, Gd3+, and Yb3+ at different temperatures and ionic strengths
Empirical model for the stability constants of acetate mono-complexes with La3+, Nd3+, Gd3+, and Yb3+ at different temperatures and ionic strengths // Journal of molecular liquids, 177 (2013), 60-62 doi:10.1016/j.molliq.2012.09.003 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 609304 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Empirical model for the stability constants of acetate mono-complexes with La3+, Nd3+, Gd3+, and Yb3+ at different temperatures and ionic strengths
Autori
Miličević, Ante ; Raos, Nenad
Izvornik
Journal of molecular liquids (0167-7322) 177
(2013);
60-62
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
lanthanides; metal complexes; prediction of stability constants
Sažetak
We developed a purely empirical model for the estimation of stability constants of acetate mono-complexes of four lanthanides (La3+, Nd3+, Gd3+, and Yb3+) at different ionic strengths (I=0.1–2.0 mol kg−1) and temperatures (t=25–70 °C). The standard errors, S.E., were 0.09, 0.05, 0.06, and 0.07, for La3+, Nd3+, Gd3+, and Yb3+ complex, respectively. We also developed common model for the complexes of all metals studied (S.E.=0.11), which enables prediction of log K1 for a metal, at different conditions, knowing the value of its constant measured at only one ionic strength and temperature.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
022-1770495-2901 - Razvoj modela za procjenu vrijednosti konstanti stabilnosti (Raos, Nenad, MZOS ) ( CroRIS)
Ustanove:
Institut za medicinska istraživanja i medicinu rada, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
