Pregled bibliografske jedinice broj: 609291
Modeling of stability constants of mono-complexes of La3+, Ce3+, Pr3+, and Nd3+ with carboxylic acids in water–dioxane solutions by using connectivity index 3χv
Modeling of stability constants of mono-complexes of La3+, Ce3+, Pr3+, and Nd3+ with carboxylic acids in water–dioxane solutions by using connectivity index 3χv // Chemical physics letters, 528 (2012), 63-67 doi:10.1016/j.cplett.2012.01.023 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 609291 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Modeling of stability constants of mono-complexes of La3+, Ce3+, Pr3+, and Nd3+ with carboxylic acids in water–dioxane solutions by using connectivity index 3χv
Autori
Miličević, Ante ; Raos, Nenad
Izvornik
Chemical physics letters (0009-2614) 528
(2012);
63-67
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
lanthanides; prediction of stability constants; acetate complexes; mixed solutions; topological indices
Sažetak
We developed two models for the estimation of stability constants in dioxane–water mixtures of monocomplexes of lanthanides (La3+, Ce3+, Pr3+, and Nd3+) with carboxylic acids (ethanoic, propanoic, and butanoic). The first, linear model proved suitable for the prediction of logK1 at low mass fractions of dioxane, w = 0–20% (r = 0.981, S.E. = 0.06), whereas the second, quadratic model, yielded better results at higher fractions, w = 40–60% (r = 0.980, S.E. = 0.10).
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut za medicinska istraživanja i medicinu rada, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
