Pregled bibliografske jedinice broj: 598224
Structure, microstructure and photoluminescence of nanocrystalline Ti-doped gahnite
Structure, microstructure and photoluminescence of nanocrystalline Ti-doped gahnite // Journal of alloys and compounds, 543 (2012), 213-220 doi:10.1016/j.jallcom.2012.07.073 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 598224 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Structure, microstructure and photoluminescence of nanocrystalline Ti-doped gahnite
Autori
Vrankić, Martina ; Gržeta, Biserka ; Mandić, Vilko ; Tkalčec, Emilija ; Milošević, Slobodan ; Čeh, Miran ; Rakvin, Boris
Izvornik
Journal of alloys and compounds (0925-8388) 543
(2012);
213-220
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
transition metal alloys and compounds ; sol-gel processing ; crystal structure ; X-ray diffraction ; transmission electron microscopy ; luminescence
Sažetak
A series of Ti-doped ZnAl2O4 (gahnite) samples with doping levels of 0, 1.8, 3.8, 5.4 and 11.6 at% Ti in relation to Al were prepared by a sol-gel technique. The samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), EPR spectroscopy, UV-vis reflectance spectroscopy and photoluminescence (PL) studies. Diffraction patterns indicated that all samples were nanocrystalline, with a spinel-type structure, space group Fd m. Titanium doping of gahnite caused an increase of unit-cell parameter and diffraction line broadening. The structure of samples was refined by the Rietveld method, simultaneously with the analysis of diffraction line broadening. TEM investigations confirmed that samples had spinel-type structure, and showed that samples contained evenly shaped particles of about 20 nm in size. Ti-doped samples exhibited strong absorption at wavelength <400 nm, and blue photoluminescence under excitation with λexc=308 nm.
Izvorni jezik
Engleski
Znanstvena područja
Fizika, Temeljne tehničke znanosti
POVEZANOST RADA
Projekti:
MZOS-035-0352851-2856 - Laserska spektroskopija hladne plazme za obradu materijala (Milošević, Slobodan, MZOS ) ( CroRIS)
MZOS-098-0982886-2893 - Dopirani optoelektronički i keramički nanomaterijali (Gržeta, Biserka, MZOS ) ( CroRIS)
MZOS-098-0982915-2939 - Molekulska struktura i dinamika sustava s paramagnetskim česticama (Ilakovac-Kveder, Marina, MZOS ) ( CroRIS)
MZOS-125-1252970-2981 - Keramički nanokompoziti dobiveni sol-gel postupkom (Kurajica, Stanislav, MZOS ) ( CroRIS)
Ustanove:
Institut za fiziku, Zagreb,
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb
Profili:
Emilija Tkalčec-Čižmek
(autor)
Slobodan Milošević
(autor)
Biserka Gržeta
(autor)
Martina Vrankić
(autor)
Vilko Mandić
(autor)
Boris Rakvin
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus