Pregled bibliografske jedinice broj: 598186
Binding Modes of Non-Spherical Anions to N-alkylammonium Resorcinarenes in the Solid State
Binding Modes of Non-Spherical Anions to N-alkylammonium Resorcinarenes in the Solid State // Crystal growth & design, 12 (2012), 10; 4919-4926 doi:10.1021/cg3008409 (međunarodna recenzija, članak, znanstveni)
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Naslov
Binding Modes of Non-Spherical Anions to N-alkylammonium Resorcinarenes in the Solid State
Autori
Beyeh, Kodiah N. ; Cetina, Mario ; Rissanen, Kari
Izvornik
Crystal growth & design (1528-7483) 12
(2012), 10;
4919-4926
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
resorcinarenes; non-spherical anions; hydrogen bonding; X-ray structure
(rResorcinarenes; non-spherical anions; hydrogen bonding; X-ray structure)
Sažetak
A series of hydrogen bond stabilized N-alkylammonium resorcinarene salts with nitrate, triflate and picrate as the counter anions were synthesized and characterized with 1H NMR and electrospray ionization (ESI) mass spectrometry. Together with electrostatic interactions, the binding of the anions with several hydrogen bond donor sites proceeds through a complex array of intra- and intermolecular hydrogen bonds, evidenced by single crystal X-ray diffraction study. These N-alkyl ammonium resorcinarenes bind the larger non-spherical anions into deformed cavitand-like structures and enforce a transformation of the resorcinarene conformation from almost symmetrical to extremely distorted.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
119-1193079-3069 - Novi organski i koordinacijski spojevi - sinteza i suodnos struktura-svojstvo (Kaitner, Branko, MZOS ) ( CroRIS)
Ustanove:
Tekstilno-tehnološki fakultet, Zagreb,
Prirodoslovno-matematički fakultet, Zagreb
Profili:
Mario Cetina
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus