Pregled bibliografske jedinice broj: 590079
Solvent-free Mechanosynthesis of Two Thermochromic Schiff Bases
Solvent-free Mechanosynthesis of Two Thermochromic Schiff Bases // Acta chimica Slovenica, 59 (2012), 3; 670-679 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 590079 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Solvent-free Mechanosynthesis of Two Thermochromic Schiff Bases
Autori
Kaitner, Branko ; Zbačnik, Marija
Izvornik
Acta chimica Slovenica (1318-0207) 59
(2012), 3;
670-679
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
solvent-free mechanosynthesis; Schiff bases; keto-enol tautomerism; thermochromism; crystal structure
Sažetak
Two thermochromic Schiff bases mostly in keto- amine tautomeric form were obtained by means of mechanochemical synthesis. Both Schiff bases Compound 1 and Compound 2, respectively are derived from the same primary amine 2- amino-5- methylphenol. Salicylaldehyde was used as aldehyde component in preparation of 1, and o-vanillin as substituted salicylaldehyde component in synthesis of 2. Powder products of the neat grinding and liquid-assisted grinding syntheses of 1 and 2 were compared with the crystalline products, obtained by recrystallization from a small amount of solvent. Both raw powder and recrystallized products were characterized and compared by means of PXRD, DSC and IR.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
119-1193079-3069 - Novi organski i koordinacijski spojevi - sinteza i suodnos struktura-svojstvo (Kaitner, Branko, MZOS ) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
