Pregled bibliografske jedinice broj: 589764
Synthesis and structure of bis- and tris-ferrocene containing N-methylimide foldamers
Synthesis and structure of bis- and tris-ferrocene containing N-methylimide foldamers // Tetrahedron, 68 (2012), 38; 7884-7891 doi:10.1016/j.tet.2012.07.031 (međunarodna recenzija, članak, znanstveni)
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Naslov
Synthesis and structure of bis- and tris-ferrocene containing N-methylimide foldamers
Autori
Kovač, Veronika ; Čakić Semenčić, Mojca ; Molčanov, Krešimir ; Sabljić, Igor ; Iveković, Damir ; Žinić, Mladen ; Rapić, Vladimir
Izvornik
Tetrahedron (0040-4020) 68
(2012), 38;
7884-7891
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
cis-cis conformation ; ferrocene ; foldamers ; helical chirality ; N-methylimides
Sažetak
The synthesis and conformational analysis of dimer Fc-CO-NMe-CO-Fc (5) and trimer Fc-CO-NMe-CO-Fn-CO-NMe-CO-Fc (6) have been described. It has been shown by means of spectroscopic studies, X-ray crystallography, and molecular modeling, that these molecules are dominated by cis-cis conformation. Furthermore, we recognized for the first time, that such type of organometallics possess elements of chiral helicity. Their crystal lattices are characterized by π-π and CH-π intermolecular interactions (5) and by CH⋯OC intermolecular hydrogen bonds (6). We believe that foldamers 5/6 are stabilized by the special type of aromatic π-π interactions between the closer cyclopentadienyl rings of the juxtaposed ferrocene units.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
058-1191344-3122 - Metalocenski biokonjugati, heterocikli i makromolekule (Kovač, Veronika, MZOS ) ( CroRIS)
098-0982904-2912 - Samo-udruživanje u gelovima i sinteza funkcionalnih hibridnih materijala (Frkanec, Leo, MZOS ) ( CroRIS)
Ustanove:
Prehrambeno-biotehnološki fakultet, Zagreb,
Institut "Ruđer Bošković", Zagreb
Profili:
Mladen Žinić
(autor)
Igor Sabljić
(autor)
Mojca Čakić
(autor)
Krešimir Molčanov
(autor)
Damir Iveković
(autor)
Vladimir Rapić
(autor)
Veronika Kovač
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE