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Pregled bibliografske jedinice broj: 589764

Synthesis and structure of bis- and tris-ferrocene containing N-methylimide foldamers


Kovač, Veronika; Čakić Semenčić, Mojca; Molčanov, Krešimir; Sabljić, Igor; Iveković, Damir; Žinić, Mladen; Rapić, Vladimir
Synthesis and structure of bis- and tris-ferrocene containing N-methylimide foldamers // Tetrahedron, 68 (2012), 38; 7884-7891 doi:10.1016/j.tet.2012.07.031 (međunarodna recenzija, članak, znanstveni)


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Naslov
Synthesis and structure of bis- and tris-ferrocene containing N-methylimide foldamers

Autori
Kovač, Veronika ; Čakić Semenčić, Mojca ; Molčanov, Krešimir ; Sabljić, Igor ; Iveković, Damir ; Žinić, Mladen ; Rapić, Vladimir

Izvornik
Tetrahedron (0040-4020) 68 (2012), 38; 7884-7891

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
cis-cis conformation ; ferrocene ; foldamers ; helical chirality ; N-methylimides

Sažetak
The synthesis and conformational analysis of dimer Fc-CO-NMe-CO-Fc (5) and trimer Fc-CO-NMe-CO-Fn-CO-NMe-CO-Fc (6) have been described. It has been shown by means of spectroscopic studies, X-ray crystallography, and molecular modeling, that these molecules are dominated by cis-cis conformation. Furthermore, we recognized for the first time, that such type of organometallics possess elements of chiral helicity. Their crystal lattices are characterized by π-π and CH-π intermolecular interactions (5) and by CH⋯OC intermolecular hydrogen bonds (6). We believe that foldamers 5/6 are stabilized by the special type of aromatic π-π interactions between the closer cyclopentadienyl rings of the juxtaposed ferrocene units.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
058-1191344-3122 - Metalocenski biokonjugati, heterocikli i makromolekule (Kovač, Veronika, MZOS ) ( CroRIS)
098-0982904-2912 - Samo-udruživanje u gelovima i sinteza funkcionalnih hibridnih materijala (Frkanec, Leo, MZOS ) ( CroRIS)

Ustanove:
Prehrambeno-biotehnološki fakultet, Zagreb,
Institut "Ruđer Bošković", Zagreb

Poveznice na cjeloviti tekst rada:

doi doi.org www.sciencedirect.com

Citiraj ovu publikaciju:

Kovač, Veronika; Čakić Semenčić, Mojca; Molčanov, Krešimir; Sabljić, Igor; Iveković, Damir; Žinić, Mladen; Rapić, Vladimir
Synthesis and structure of bis- and tris-ferrocene containing N-methylimide foldamers // Tetrahedron, 68 (2012), 38; 7884-7891 doi:10.1016/j.tet.2012.07.031 (međunarodna recenzija, članak, znanstveni)
Kovač, V., Čakić Semenčić, M., Molčanov, K., Sabljić, I., Iveković, D., Žinić, M. & Rapić, V. (2012) Synthesis and structure of bis- and tris-ferrocene containing N-methylimide foldamers. Tetrahedron, 68 (38), 7884-7891 doi:10.1016/j.tet.2012.07.031.
@article{article, author = {Kova\v{c}, Veronika and \v{C}aki\'{c} Semen\v{c}i\'{c}, Mojca and Mol\v{c}anov, Kre\v{s}imir and Sablji\'{c}, Igor and Ivekovi\'{c}, Damir and \v{Z}ini\'{c}, Mladen and Rapi\'{c}, Vladimir}, year = {2012}, pages = {7884-7891}, DOI = {10.1016/j.tet.2012.07.031}, keywords = {cis-cis conformation, ferrocene, foldamers, helical chirality, N-methylimides}, journal = {Tetrahedron}, doi = {10.1016/j.tet.2012.07.031}, volume = {68}, number = {38}, issn = {0040-4020}, title = {Synthesis and structure of bis- and tris-ferrocene containing N-methylimide foldamers}, keyword = {cis-cis conformation, ferrocene, foldamers, helical chirality, N-methylimides} }
@article{article, author = {Kova\v{c}, Veronika and \v{C}aki\'{c} Semen\v{c}i\'{c}, Mojca and Mol\v{c}anov, Kre\v{s}imir and Sablji\'{c}, Igor and Ivekovi\'{c}, Damir and \v{Z}ini\'{c}, Mladen and Rapi\'{c}, Vladimir}, year = {2012}, pages = {7884-7891}, DOI = {10.1016/j.tet.2012.07.031}, keywords = {cis-cis conformation, ferrocene, foldamers, helical chirality, N-methylimides}, journal = {Tetrahedron}, doi = {10.1016/j.tet.2012.07.031}, volume = {68}, number = {38}, issn = {0040-4020}, title = {Synthesis and structure of bis- and tris-ferrocene containing N-methylimide foldamers}, keyword = {cis-cis conformation, ferrocene, foldamers, helical chirality, N-methylimides} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus
  • MEDLINE


Citati:





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