Pregled bibliografske jedinice broj: 588980
Spectroscopic Studies of Methimazole Reactivity toward the Aquapentacyanoferrate (II) Ion in Aqueous Solutions
Spectroscopic Studies of Methimazole Reactivity toward the Aquapentacyanoferrate (II) Ion in Aqueous Solutions // Spectroscopy, 27 (2012), 5/6; 509-514 (međunarodna recenzija, članak, znanstveni)
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Naslov
Spectroscopic Studies of Methimazole Reactivity toward the Aquapentacyanoferrate (II) Ion in Aqueous Solutions
Autori
Cvijanović, Danijela ; Damjanović, Vladimir ; Picek, Igor ; Foretić, Blaženka
Izvornik
Spectroscopy (0712-4813) 27
(2012), 5/6;
509-514
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
2-mercapto-1-methylimidazole; pentacyanoferrate(II) complexes; spectroscopy
Sažetak
Methimazole (2-mercapto-1-methylimidazole, MMI) and its pentacyanoferrate (II) complex have been characterized by means of UV/Vis, Raman, and NMR spectroscopy. The reaction of MMI with aquapentacyanoferrate (II), [Fe(CN)5(H2O)]3−, in buffered aqueous solutions yielded the [Fe(CN)5(MMI)]3− complex. It was found that only thione tautomer of MMI coordinates to the iron (II). The exceptionally stabile and inert complex was produced.
Izvorni jezik
Engleski
Znanstvena područja
Kemija, Temeljne medicinske znanosti
POVEZANOST RADA
Projekti:
108-1193079-3070 - Kompleksi željeza i biološki aktivnih liganada (Foretić, Blaženka, MZOS ) ( CroRIS)
Ustanove:
Medicinski fakultet, Zagreb
Profili:
Vladimir Damjanović (autor)
Danijela Cvijanović (autor)
Igor Picek (autor)
Blaženka Foretić (autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus