An Expeditious Method for the Preparation of 2- Hydroxy-1, 4-dioxane and Its Use in Reductive Alkylation of Amines

Vinter, Adrijana; Avdagić, Amir; Štimac, Vlado; Palej, Ivana; Čikoš, Ana; Šunjić, Vitomir; Alihodžić, Sulejman

doi:10.1055/s-0029-1217101

Pregled bibliografske jedinice broj: 588607

An Expeditious Method for the Preparation of 2- Hydroxy-1, 4-dioxane and Its Use in Reductive Alkylation of Amines

Vinter, Adrijana; Avdagić, Amir; Štimac, Vlado; Palej, Ivana; Čikoš, Ana; Šunjić, Vitomir; Alihodžić, Sulejman

An Expeditious Method for the Preparation of 2- Hydroxy-1, 4-dioxane and Its Use in Reductive Alkylation of Amines // Synthesis, 42 (2010), 2; 255-258 doi:10.1055/s-0029-1217101 (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 588607 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
An Expeditious Method for the Preparation of 2- Hydroxy-1, 4-dioxane and Its Use in Reductive Alkylation of Amines

Autori
Vinter, Adrijana ; Avdagić, Amir ; Štimac, Vlado ; Palej, Ivana ; Čikoš, Ana ; Šunjić, Vitomir ; Alihodžić, Sulejman

Izvornik
Synthesis (0039-7881) 42 (2010), 2; 255-258

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
diethylene glycol - oxidations - reductive alkylations - 2-hydroxy-1; 4-dioxane - ruthenium(VIII) catalysis

Sažetak
Selective oxidation of diethylene glycol by a ruthenium(VIII) species, obtained in situ from ruthenium(III) chloride-sodium periodate in the presence of a catalytic quantity of water, affords a monoaldehyde in the form of the internal acetal 2-hydroxy-1, 4-dioxane. This compound was used in reductive alkylations of selected primary and secondary amines, demonstrating its utility in the preparation of target structures with the 2-(2- hydroxyethoxy)ethylamino unit.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA

Ustanove:
Fidelta d.o.o.

Profili:

Amir Avdagić (autor)