Pregled bibliografske jedinice broj: 579267
X-ray diffraction and Fourier transform-infrared analysis of the rust formed by corrosion of steel in aqueous solutions
X-ray diffraction and Fourier transform-infrared analysis of the rust formed by corrosion of steel in aqueous solutions // Journal of materials science, 28 (1993), 21; 5744-5752 doi:10.1007/BF00365176 (međunarodna recenzija, članak, znanstveni)
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Naslov
X-ray diffraction and Fourier transform-infrared
analysis of the rust formed by corrosion of steel
in aqueous solutions
Autori
Musić, Svetozar ; Gotić, Marijan ; Popović, Stanko
Izvornik
Journal of materials science (0022-2461) 28
(1993), 21;
5744-5752
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
amorphous fraction ; electrolytes ; ferrihydrite ; Fourier transform infrared spectroscopy ; goethite ; haematite ; ions ; lepidocrocite ; magnetite ; phase compositions ; rust ; steel corrosion ; X ray diffraction analysis
Sažetak
Chemical and structural properties of the rust formed by corrosion of steel in aqueous solutions were studied by X-ray diffraction and Fourier transform infrared (FT-IR) spectroscopy. The corrosion products of steel were generated in aqueous solutions of different electrolyte compositions at room temperature (20 °C) or in an autoclave at 120 °C. X-ray diffraction analysis showed the presence of different oxide phases in the rust, such as lepidocrocite, magnetite, ferrihydrite, goethite and haematite. In all samples, the presence of an amorphous fraction was detected. Ferrihydrite was detected only in the rust samples formed at 120 °C, The characteristic properties of the FT-IR spectrum of the ferrihydrite component in the rust were investigated. Phase compositions of the corrosion products depended on the formation temperature and the electrolyte composition of the aqueous solutions. The influence of chloride, nitrate or sulphate anions on the phase composition of the rust is discussed.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus