Pregled bibliografske jedinice broj: 576786
Ferrocenyl-Labeled Sugar Amino Acids: Conformation and Properties
Ferrocenyl-Labeled Sugar Amino Acids: Conformation and Properties // Organometallics, 31 (2012), 9; 3683-3694 doi:10.1021/om300174p (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 576786 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Ferrocenyl-Labeled Sugar Amino Acids: Conformation and Properties
Autori
Förster, Christoph ; Kovačević, Monika ; Barišić, Lidija ; Rapić, Vladimir ; Heinze, Katja
Izvornik
Organometallics (0276-7333) 31
(2012), 9;
3683-3694
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
conformational analysis; hydrogen bonds; metallocenes; redox chemistry; sugar amino acids
Sažetak
Novel organometallic sugar amino acid conjugates 1–5 have been prepared by amide coupling of O-protected N-acetylmuramic acid and iso-muramic acid (2-[3-amino-2, 5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxypropanoic acid) with 1-aminoferrocene, 1-aminoferrocene-1′-carboxylic acid (H-Fca-OH), or 1, 1′-diaminoferrocene, respectively. The influence of the ferrocenyl moiety and presence of additional remote potential hydrogen atom acceptors and donors at the ferrocenyl core on the conformation and lipophilicity is investigated by TLC, IR, NMR, and CD spectroscopic methods augmented by density functional calculations. Furthermore, the redox potential of the ferrocene/ferrocenium couple is tuned by the electron-withdrawing and -donating nature of the substituents at the ferrocenyl label.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
058-1191344-3122 - Metalocenski biokonjugati, heterocikli i makromolekule (Kovač, Veronika, MZOS ) ( CroRIS)
Ustanove:
Prehrambeno-biotehnološki fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
