Pregled bibliografske jedinice broj: 527500
Lipase-catalyzed kinetic resolution of racemic 1-(10-alkyl-10H-phenothiazin-3-yl)ethanols and their butanoates
Lipase-catalyzed kinetic resolution of racemic 1-(10-alkyl-10H-phenothiazin-3-yl)ethanols and their butanoates // Tetrahedron: asymmetry, 21 (2010), 16; 1993-1998 doi:10.1016/j.tetasy.2010.06.007 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 527500 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Lipase-catalyzed kinetic resolution of racemic 1-(10-alkyl-10H-phenothiazin-3-yl)ethanols and their butanoates
Autori
Brem, Jürgen ; Toşa, Monica-Ioana ; Paizs, Csaba ; Munceanu, Anca ; Matković-Čalogović, Dubravka ; Irimie, Florin-Dan
Izvornik
Tetrahedron: asymmetry (0957-4166) 21
(2010), 16;
1993-1998
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
kinetic resolution; lipase; X-ray crystallography
Sažetak
The synthesis of both enantiomers of 1-(10-alkyl-10H-phenothiazin-3-yl)ethanols and their butanoates by enantiomer-selective acylation of racemic alcohols with the lipase from Pseudomonas fluorescens (L-AK) or/and by methanolysis of the corresponding racemic esters with lipase B from Candida antarctica (CaL-B) is described. The absolute configuration of the enantiomerically pure enantiomers was determined by X-ray crystallography.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
119-1193079-1084 - Strukturno istraživanje bioloških makromolekula metodom rentgenske difrakcije (Matković-Čalogović, Dubravka, MZOS ) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Profili:
Dubravka Matković-Čalogović
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
