Pregled bibliografske jedinice broj: 525034
EPR studies of the 3D anionic networks {;[Cu(bpy)3][M2(C2O4)3]•H2O};n (M=Cu2+, Mn2+)
EPR studies of the 3D anionic networks {;[Cu(bpy)3][M2(C2O4)3]•H2O};n (M=Cu2+, Mn2+) // Abstract book of The Second international workshop on "Recent advances in broad-band solid-state NMR of correlated electronic systems"
Trogir, 2011. str. 61-61 (poster, međunarodna recenzija, sažetak, znanstveni)
CROSBI ID: 525034 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
EPR studies of the 3D anionic networks {;[Cu(bpy)3][M2(C2O4)3]•H2O};n (M=Cu2+, Mn2+)
Autori
Žilić, Dijana ; Rakvin, Boris ; Jurić, Marijana
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
Abstract book of The Second international workshop on "Recent advances in broad-band solid-state NMR of correlated electronic systems"
/ - Trogir, 2011, 61-61
Skup
The Second international workshop on "Recent advances in broad-band solid-state NMR of correlated electronic systems"
Mjesto i datum
Trogir, Hrvatska, 04.09.2011. - 09.09.2011
Vrsta sudjelovanja
Poster
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
EPR; bakar(II); mangan(II)
(EPR; copper(II); manganese(II))
Sažetak
The homometallic {;[Cu(bpy)3][Cu2(C2O4)3]·H2O};n (1) and the heterometallic {;[Cu(bpy)3][Mn2(C2O4)3]·H2O};n (2) compounds (bpy = 2, 2'-bipyridine) have been synthesized. The structures of both compounds consist of a 3D, polimeric anionic network [M2(C2O4)3]n2n– (where M = Cu2+ or Mn2+) with cations [Cu(bpy)3]2+ occupying the vacancies of the framework. So far, only a few single-crystal structures of this type of 3D metal oxalates have been described. Electron paramagnetic resonance (EPR) measurements performed by an X-band spectrometer on a polycrystalline sample of 1 and on a single crystal of 2, in the temperature range 300–5 K, are presented.
Izvorni jezik
Engleski
Znanstvena područja
Fizika, Kemija
POVEZANOST RADA
Projekti:
098-0982904-2946 - Višenuklearni metalni sustavi: sinteza i svojstva (Perić, Berislav, MZOS ) ( CroRIS)
098-0982915-2939 - Molekulska struktura i dinamika sustava s paramagnetskim česticama (Ilakovac-Kveder, Marina, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
