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Pregled bibliografske jedinice broj: 522752

N–H•••O=P hydrogen-bonded dimers as the main structural motif of aminophosphonate diesters


Juribašić, Marina; Bellotto, Lisa; Tušek-Božić, Ljerka
N–H•••O=P hydrogen-bonded dimers as the main structural motif of aminophosphonate diesters // Structural chemistry, 23 (2012), 1; 257-266 doi:10.1007/s11224-011-9859-z (međunarodna recenzija, članak, znanstveni)


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Naslov
N–H•••O=P hydrogen-bonded dimers as the main structural motif of aminophosphonate diesters

Autori
Juribašić, Marina ; Bellotto, Lisa ; Tušek-Božić, Ljerka

Izvornik
Structural chemistry (1040-0400) 23 (2012), 1; 257-266

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
aminophosphonate; hydrogen-bonded dimers; X-ray structure analysis; ESI mass spectrometry

Sažetak
Crystal and molecular structures of three aminophosphonate diesters, diethyl and dibutyl [alpha-(quinolin-3-ylamino)-N-benzyl]phosphonates (1 and 2) and dibutyl [alpha-anilino-(quinolin-3-yl)methyl]phosphonate (3) were reported and comparatively discussed. Characteristic structural feature for these compounds are strong N–H•••O=P hydrogen bonds that connect two organophosphorus molecules in cyclic centrosymmetric dimer. Phosphoryl oxygen forms additional interaction with a C–H donor from the nearby aromatic group. Dimer formation in solution was also confirmed using electrospray ionization mass spectrometry. Mass spectra of six structurally similar aminophosphonate derivatives, 1-3 along with diethyl [alpha-anilino-(quinolin-3-yl)methyl]phosphonate (4), diethyl and dibutyl [alpha-anilino-(quinolin-2-yl)methyl]phosphonates (5 and 6) were studied and dimolecular ions [2M+Na]+ and [2M+H]+ were observed.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
098-0982915-2950 - Dizajn, sinteza i svojstva organskih liganada i njihovih metalnih kompleksa (Ćurić, Manda, MZOS ) ( CroRIS)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Poveznice na cjeloviti tekst rada:

doi www.springerlink.com

Citiraj ovu publikaciju:

Juribašić, Marina; Bellotto, Lisa; Tušek-Božić, Ljerka
N–H•••O=P hydrogen-bonded dimers as the main structural motif of aminophosphonate diesters // Structural chemistry, 23 (2012), 1; 257-266 doi:10.1007/s11224-011-9859-z (međunarodna recenzija, članak, znanstveni)
Juribašić, M., Bellotto, L. & Tušek-Božić, L. (2012) N–H•••O=P hydrogen-bonded dimers as the main structural motif of aminophosphonate diesters. Structural chemistry, 23 (1), 257-266 doi:10.1007/s11224-011-9859-z.
@article{article, author = {Juriba\v{s}i\'{c}, Marina and Bellotto, Lisa and Tu\v{s}ek-Bo\v{z}i\'{c}, Ljerka}, year = {2012}, pages = {257-266}, DOI = {10.1007/s11224-011-9859-z}, keywords = {aminophosphonate, hydrogen-bonded dimers, X-ray structure analysis, ESI mass spectrometry}, journal = {Structural chemistry}, doi = {10.1007/s11224-011-9859-z}, volume = {23}, number = {1}, issn = {1040-0400}, title = {N–H•••O=P hydrogen-bonded dimers as the main structural motif of aminophosphonate diesters}, keyword = {aminophosphonate, hydrogen-bonded dimers, X-ray structure analysis, ESI mass spectrometry} }
@article{article, author = {Juriba\v{s}i\'{c}, Marina and Bellotto, Lisa and Tu\v{s}ek-Bo\v{z}i\'{c}, Ljerka}, year = {2012}, pages = {257-266}, DOI = {10.1007/s11224-011-9859-z}, keywords = {aminophosphonate, hydrogen-bonded dimers, X-ray structure analysis, ESI mass spectrometry}, journal = {Structural chemistry}, doi = {10.1007/s11224-011-9859-z}, volume = {23}, number = {1}, issn = {1040-0400}, title = {N–H•••O=P hydrogen-bonded dimers as the main structural motif of aminophosphonate diesters}, keyword = {aminophosphonate, hydrogen-bonded dimers, X-ray structure analysis, ESI mass spectrometry} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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