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Pregled bibliografske jedinice broj: 520094

Unprecedented Molecular Dynamics in the Solid State Induced During Mechanochemical Synthesis of Azobenzene/Triphenylphosphine Palladacycles

Juribašić, Marina; Cinčić, Dominik; Molčanov, Krešimir; Šket, Primož; Plavec, Janez; Babić, Darko; Ćurić, Manda
Unprecedented Molecular Dynamics in the Solid State Induced During Mechanochemical Synthesis of Azobenzene/Triphenylphosphine Palladacycles // XIX EuCOMC, 19th EuCheMS International Conference on Organometallic Chemistry, Book of Abstracts / Kalck, Phillipe ; Poli, Rinaldo (ur.).
Toulouse, 2011. str. P011-P011 (poster, međunarodna recenzija, sažetak, znanstveni)

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Naslov
Unprecedented Molecular Dynamics in the Solid State Induced During Mechanochemical Synthesis of Azobenzene/Triphenylphosphine Palladacycles

Autori
Juribašić, Marina ; Cinčić, Dominik ; Molčanov, Krešimir ; Šket, Primož ; Plavec, Janez ; Babić, Darko ; Ćurić, Manda

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
XIX EuCOMC, 19th EuCheMS International Conference on Organometallic Chemistry, Book of Abstracts / Kalck, Phillipe ; Poli, Rinaldo - Toulouse, 2011, P011-P011

Skup
XIX EuCOMC, 19th EuCheMS International Conference on Organometallic Chemistry

Mjesto i datum
Toulouse, Francuska, 03.07.2011. - 08.07.2011

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
mechanochemistry; cyclopalladated azobenzenes; triphenylphosphine; X-ray diffraction; MAS NMR; DFT

Sažetak
We have prepared the first triphenylphosphine derivatives of dicyclopalladated azobenzene complexes by two different preparative methods: grinding and conventional solution-based reactions. Both synthetic routes have produced the same thermodynamically favorable halogen-bridged dipalladium complexes (1a-4a) and have demonstrated for the first time the possibility of very complex molecular dynamics in the solid state (Scheme 1). Structural and photophysical properties of novel complexes have been characterized by experimental (X-ray analysis, 1H and 31P NMR, UV-visible and fluorescence spectroscopies) and computational methods. The obtained results are important for understanding of the structural transformations occurring during mechanical processing of solid reactants and will have significant implication for the future design and synthesis of new coordination compounds.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Projekti:
098-0982915-2942 - Razvoj matematičkih metoda za opis strukture, dinamike i reaktivnosti molekula (Babić, Darko, MZOS ) ( CroRIS)
098-0982915-2950 - Dizajn, sinteza i svojstva organskih liganada i njihovih metalnih kompleksa (Ćurić, Manda, MZOS ) ( CroRIS)
098-1191344-2943 - Protein-ligand međudjelovanja na atomnoj razini (Luić, Marija, MZOS ) ( CroRIS)
119-1193079-3069 - Novi organski i koordinacijski spojevi - sinteza i suodnos struktura-svojstvo (Kaitner, Branko, MZOS ) ( CroRIS)

Ustanove:
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb

Profili:

Avatar Url Marina Juribašić Kulcsar (autor)

Avatar Url Dominik Cinčić (autor)

Avatar Url Manda Ćurić (autor)

Avatar Url Darko Babić (autor)

Avatar Url Krešimir Molčanov (autor)

Citiraj ovu publikaciju:

Juribašić, Marina; Cinčić, Dominik; Molčanov, Krešimir; Šket, Primož; Plavec, Janez; Babić, Darko; Ćurić, Manda
Unprecedented Molecular Dynamics in the Solid State Induced During Mechanochemical Synthesis of Azobenzene/Triphenylphosphine Palladacycles // XIX EuCOMC, 19th EuCheMS International Conference on Organometallic Chemistry, Book of Abstracts / Kalck, Phillipe ; Poli, Rinaldo (ur.).
Toulouse, 2011. str. P011-P011 (poster, međunarodna recenzija, sažetak, znanstveni)
Juribašić, M., Cinčić, D., Molčanov, K., Šket, P., Plavec, J., Babić, D. & Ćurić, M. (2011) Unprecedented Molecular Dynamics in the Solid State Induced During Mechanochemical Synthesis of Azobenzene/Triphenylphosphine Palladacycles. U: Kalck, P. & Poli, R. (ur.)XIX EuCOMC, 19th EuCheMS International Conference on Organometallic Chemistry, Book of Abstracts.
@article{article, author = {Juriba\v{s}i\'{c}, Marina and Cin\v{c}i\'{c}, Dominik and Mol\v{c}anov, Kre\v{s}imir and \v{S}ket, Primo\v{z} and Plavec, Janez and Babi\'{c}, Darko and \'{C}uri\'{c}, Manda}, year = {2011}, pages = {P011-P011}, keywords = {mechanochemistry, cyclopalladated azobenzenes, triphenylphosphine, X-ray diffraction, MAS NMR, DFT}, title = {Unprecedented Molecular Dynamics in the Solid State Induced During Mechanochemical Synthesis of Azobenzene/Triphenylphosphine Palladacycles}, keyword = {mechanochemistry, cyclopalladated azobenzenes, triphenylphosphine, X-ray diffraction, MAS NMR, DFT}, publisherplace = {Toulouse, Francuska} }
@article{article, author = {Juriba\v{s}i\'{c}, Marina and Cin\v{c}i\'{c}, Dominik and Mol\v{c}anov, Kre\v{s}imir and \v{S}ket, Primo\v{z} and Plavec, Janez and Babi\'{c}, Darko and \'{C}uri\'{c}, Manda}, year = {2011}, pages = {P011-P011}, keywords = {mechanochemistry, cyclopalladated azobenzenes, triphenylphosphine, X-ray diffraction, MAS NMR, DFT}, title = {Unprecedented Molecular Dynamics in the Solid State Induced During Mechanochemical Synthesis of Azobenzene/Triphenylphosphine Palladacycles}, keyword = {mechanochemistry, cyclopalladated azobenzenes, triphenylphosphine, X-ray diffraction, MAS NMR, DFT}, publisherplace = {Toulouse, Francuska} }

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