Naslov
Phosphine ligated ruthenium(III) complex in catalysis of transfer hydrogenation of ketones

Autori
Zhou, Cheng-Liang ; Popović, Zora ; Đaković, Marijana ; Wu, Hai-Hong ; Liu, Ye

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
The twenthieth Croatian-Slovenian meeting - CSCM20, Book of Abstracts and Programme / - Zagreb : Hrvatska akademija znanosti i umjetnosti (HAZU) ; Hrvatska Kristalografska Zajednica, 2011, 6-6

Skup
The twentieth Croatian-Slovenian meeting - CSCM20

Mjesto i datum
Baška, Hrvatska, 15.06.2011. - 19.06.2011

Vrsta sudjelovanja
Predavanje

Vrsta recenzije
Nije recenziran

Ključne riječi
catalysis; ruthenium(III) complex; crystal structure; transfer hydrogenation

Sažetak
The reduction of carbonyl compounds to alcohols is an industrially relevant reaction for the preparation of fine chemicals, perfumes, agrochemicals, and pharmaceuticals.1 Metal-catalyzed transformation from carbonyl compounds to alcohols includes H2 hydrogenation, transfer hydrogenation, or hydrosilylation.1 In particular, transfer hydrogenation is a potential useful protocol whereby unsaturated compounds can be hydrogenated without the use of molecular H2, thus enhancing operational simplicity and reducing high pressure induced risk. A large number of ruthenium(II) complexes bearing phosphines have become the most prominent catalysts for transfer hydrogenation. However, to the best of our knowledge, the syntheses of phosphine-ligated ruthenium(III) complexes and their application to transfer hydrogenation are rarely reported.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA