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Pregled bibliografske jedinice broj: 499598

Preparation, spectroscopic characterization and crystal structures of ferrocenylalkanediols and derived acetates

Lapić, Jasmina; Bilić, Josipa; Cetina, Mario; Djaković, Senka; Rapić, Vladimir
Preparation, spectroscopic characterization and crystal structures of ferrocenylalkanediols and derived acetates // Journal of molecular structure, 985 (2011), 2/3; 413-418 doi:10.1016/j.molstruc.2010.11.040 (međunarodna recenzija, članak, znanstveni)

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Naslov
Preparation, spectroscopic characterization and crystal structures of ferrocenylalkanediols and derived acetates

Autori
Lapić, Jasmina ; Bilić, Josipa ; Cetina, Mario ; Djaković, Senka ; Rapić, Vladimir

Izvornik
Journal of molecular structure (0022-2860) 985 (2011), 2/3; 413-418

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
ferrocenylalkanediols and acetates; meso; dl-diol; X-ray diffraction; Self-assembly

Sažetak
(eso, dl)-3-(ferrocenylmethyl)pentane-2, 4-diol (3) was synthesized by reduction of 3-(ferrocenylmethyl)pentane-2, 4-dione (2) with LiAlH4 in a good yield and corresponding monoacetate 4 and diacetate 5 were prepared. Newly prepared compounds are characterized by elemental analysis, IR and NMR spectroscopy and will be used as a substrate or standards for lipase mediated desymmetrization. The structures of 3-(ferrocenylmethyl)pentane-2, 4-diol (3) and 2-(ferrocenylmethyl)propane-1, 3-diol diacetate (8), which is derived from prochiral 2-(ferrocenylmethyl)propane-1, 2-diol (6), were determined by X-ray crystal structure analysis. The conformation of the cyclopentadienyl rings is eclipsed in 3 and almost halfway between eclipsed and staggered in 8. One O−H...O hydrogen bond links the molecules of diol 3 into chains, while one weak C−H...π interaction self-assembles the molecules of diacetate 8 into dimers.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Projekti:
058-1191344-3122 - Metalocenski biokonjugati, heterocikli i makromolekule (Kovač, Veronika, MZOS ) ( CroRIS)
119-1193079-3069 - Novi organski i koordinacijski spojevi - sinteza i suodnos struktura-svojstvo (Kaitner, Branko, MZOS ) ( CroRIS)

Ustanove:
Prehrambeno-biotehnološki fakultet, Zagreb,
Tekstilno-tehnološki fakultet, Zagreb,
Prirodoslovno-matematički fakultet, Zagreb

Profili:

Avatar Url Senka Djaković (autor)

Avatar Url Mario Cetina (autor)

Avatar Url Jasmina Lapić (autor)

Avatar Url Josipa Bilić (autor)

Avatar Url Vladimir Rapić (autor)

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com www.sciencedirect.com

Citiraj ovu publikaciju:

Lapić, Jasmina; Bilić, Josipa; Cetina, Mario; Djaković, Senka; Rapić, Vladimir
Preparation, spectroscopic characterization and crystal structures of ferrocenylalkanediols and derived acetates // Journal of molecular structure, 985 (2011), 2/3; 413-418 doi:10.1016/j.molstruc.2010.11.040 (međunarodna recenzija, članak, znanstveni)
Lapić, J., Bilić, J., Cetina, M., Djaković, S. & Rapić, V. (2011) Preparation, spectroscopic characterization and crystal structures of ferrocenylalkanediols and derived acetates. Journal of molecular structure, 985 (2/3), 413-418 doi:10.1016/j.molstruc.2010.11.040.
@article{article, author = {Lapi\'{c}, Jasmina and Bili\'{c}, Josipa and Cetina, Mario and Djakovi\'{c}, Senka and Rapi\'{c}, Vladimir}, year = {2011}, pages = {413-418}, DOI = {10.1016/j.molstruc.2010.11.040}, keywords = {ferrocenylalkanediols and acetates, meso, dl-diol, X-ray diffraction, Self-assembly}, journal = {Journal of molecular structure}, doi = {10.1016/j.molstruc.2010.11.040}, volume = {985}, number = {2/3}, issn = {0022-2860}, title = {Preparation, spectroscopic characterization and crystal structures of ferrocenylalkanediols and derived acetates}, keyword = {ferrocenylalkanediols and acetates, meso, dl-diol, X-ray diffraction, Self-assembly} }
@article{article, author = {Lapi\'{c}, Jasmina and Bili\'{c}, Josipa and Cetina, Mario and Djakovi\'{c}, Senka and Rapi\'{c}, Vladimir}, year = {2011}, pages = {413-418}, DOI = {10.1016/j.molstruc.2010.11.040}, keywords = {ferrocenylalkanediols and acetates, meso, dl-diol, X-ray diffraction, Self-assembly}, journal = {Journal of molecular structure}, doi = {10.1016/j.molstruc.2010.11.040}, volume = {985}, number = {2/3}, issn = {0022-2860}, title = {Preparation, spectroscopic characterization and crystal structures of ferrocenylalkanediols and derived acetates}, keyword = {ferrocenylalkanediols and acetates, meso, dl-diol, X-ray diffraction, Self-assembly} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus

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