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Pregled bibliografske jedinice broj: 481763

Self-assembling of dihydroxypropyl 5, 6-dihydrothymine derivatives

Cetina, Mario; Makarević, Janja; Nura-Lama, A.
Self-assembling of dihydroxypropyl 5, 6-dihydrothymine derivatives // Journal of molecular structure, 980 (2010), 1-3; 156-162 doi:10.1016/j.molstruc.2010.06.045 (međunarodna recenzija, članak, znanstveni)

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Naslov
Self-assembling of dihydroxypropyl 5, 6-dihydrothymine derivatives

Autori
Cetina, Mario ; Makarević, Janja ; Nura-Lama, A.

Izvornik
Journal of molecular structure (0022-2860) 980 (2010), 1-3; 156-162

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
5 ; 6-Dihydrothymine derivatives ; X-ray diffraction ; Self-assembly ; Acyclic nucleosides ; Aliphatic nucleosides ; Antiviral and antitumor activities

Sažetak
(R, S)-1-(2', 3'-Dibenzoyloxypropyl)-5, 6-dihydrothymine (2) was synthesized from (R, S)-1-(2', 3'-dihydroxypropyl)-5, 6-dihydrothymine and its structure has been analyzed by X-ray diffraction, NMR and FTIR spectroscopic methods. The molecular structure and supramolecular assembling of 2 is compared with the structure of its dimesyloxypropyl analogue (1). Compound 1 crystallizes as cocrystal of two diastereoisomers, while 2 crystallizes as a racemic mixture. Main hydrogen-bonded motif in both compounds is dimer formed by pair of N-H•••O(=C) hydrogen bonds, which are further linked by C-H•••O hydrogen bonds. Phenyl rings of dibenzoyldihydropyrimidine moieties of 2 participate also in supramolecular aggregation via three C-H•••Pi interactions. Hydrogen bonding as driving force of 2 self-assembly was proving by the NMR and FTIR spectroscopy.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Projekti:
098-0982904-2912 - Samo-udruživanje u gelovima i sinteza funkcionalnih hibridnih materijala (Frkanec, Leo, MZOS ) ( CroRIS)
119-1193079-3069 - Novi organski i koordinacijski spojevi - sinteza i suodnos struktura-svojstvo (Kaitner, Branko, MZOS ) ( CroRIS)

Ustanove:
Institut "Ruđer Bošković", Zagreb,
Tekstilno-tehnološki fakultet, Zagreb

Profili:

Avatar Url Mario Cetina (autor)

Avatar Url Janja Makarević (autor)

Poveznice na cjeloviti tekst rada:

doi dx.doi.org www.sciencedirect.com

Citiraj ovu publikaciju:

Cetina, Mario; Makarević, Janja; Nura-Lama, A.
Self-assembling of dihydroxypropyl 5, 6-dihydrothymine derivatives // Journal of molecular structure, 980 (2010), 1-3; 156-162 doi:10.1016/j.molstruc.2010.06.045 (međunarodna recenzija, članak, znanstveni)
Cetina, M., Makarević, J. & Nura-Lama, A. (2010) Self-assembling of dihydroxypropyl 5, 6-dihydrothymine derivatives. Journal of molecular structure, 980 (1-3), 156-162 doi:10.1016/j.molstruc.2010.06.045.
@article{article, author = {Cetina, Mario and Makarevi\'{c}, Janja and Nura-Lama, A.}, year = {2010}, pages = {156-162}, DOI = {10.1016/j.molstruc.2010.06.045}, keywords = {5, 6-Dihydrothymine derivatives, X-ray diffraction, Self-assembly, Acyclic nucleosides, Aliphatic nucleosides, Antiviral and antitumor activities}, journal = {Journal of molecular structure}, doi = {10.1016/j.molstruc.2010.06.045}, volume = {980}, number = {1-3}, issn = {0022-2860}, title = {Self-assembling of dihydroxypropyl 5, 6-dihydrothymine derivatives}, keyword = {5, 6-Dihydrothymine derivatives, X-ray diffraction, Self-assembly, Acyclic nucleosides, Aliphatic nucleosides, Antiviral and antitumor activities} }
@article{article, author = {Cetina, Mario and Makarevi\'{c}, Janja and Nura-Lama, A.}, year = {2010}, pages = {156-162}, DOI = {10.1016/j.molstruc.2010.06.045}, keywords = {5, 6-Dihydrothymine derivatives, X-ray diffraction, Self-assembly, Acyclic nucleosides, Aliphatic nucleosides, Antiviral and antitumor activities}, journal = {Journal of molecular structure}, doi = {10.1016/j.molstruc.2010.06.045}, volume = {980}, number = {1-3}, issn = {0022-2860}, title = {Self-assembling of dihydroxypropyl 5, 6-dihydrothymine derivatives}, keyword = {5, 6-Dihydrothymine derivatives, X-ray diffraction, Self-assembly, Acyclic nucleosides, Aliphatic nucleosides, Antiviral and antitumor activities} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus

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