Pretraga

Pretražite po imenu i prezimenu autora, mentora, urednika, prevoditelja

Napredna pretraga

Pregled bibliografske jedinice broj: 462612

Synthesis, X-ray and spectroscopic analysis of 2-chloro-4-(methoxymethyl)-6-methyl-5- nitropyridine-3-carbonitrile

Jukić, Marijana; Cetina, Mario; Halambek, Jasna; Ugarković, Ivana
Synthesis, X-ray and spectroscopic analysis of 2-chloro-4-(methoxymethyl)-6-methyl-5- nitropyridine-3-carbonitrile // Journal of molecular structure, 979 (2010), 1/3; 108-114 doi:10.1016/j.molstruc.2010.06.012 (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 462612 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Synthesis, X-ray and spectroscopic analysis of 2-chloro-4-(methoxymethyl)-6-methyl-5- nitropyridine-3-carbonitrile

Autori
Jukić, Marijana ; Cetina, Mario ; Halambek, Jasna ; Ugarković, Ivana

Izvornik
Journal of molecular structure (0022-2860) 979 (2010), 1/3; 108-114

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
substituted pyridine; X-ray diffraction; IR; NMR and UV-vis spectroscopy

Sažetak
Compound 2-chloro-4-(methoxymethyl)-6-methyl-5-nitropyridine-3-carbonitrile (2) has been obtained from 4-(methoxymethyl)-6-methyl-5-nitro-2-oxo-1, 2-dihydropyridine-3-carbonitrile (1) by novel protocol using Vilsmeier-Haack chlorination and its solid state structure was analyzed using Xray analysis. Structural features have been also studied by IR, NMR and electronic spectroscopy, and the optical properties were investigated by UV-vis absorption and fluorescence spectroscopy. Compound 2 crystallizes with two independent molecules in the asymmetric unit with almost identical geometric parameters. One C-H...O hydrogen bond self-assembles one type of independent molecule into chains, while second type is linked by one weak aromatic pi...pi stacking interaction. The absorption and fluorescence maximum of compound 2 were observed at 290 nm and 480 nm, respectively. The effects of solvents were investigated and interpreted on the emission spectra in protic and aprotic solvents in the range 200-600 nm.

Izvorni jezik
Engleski

Znanstvena područja
Kemija, Biotehnologija



POVEZANOST RADA

Projekti:
058-0582261-2253 - Ekološke priprave i elektrokemijska karakterizacija biološki aktivnih spojeva (Jukić, Marijana, MZOS ) ( CroRIS)
119-1193079-3069 - Novi organski i koordinacijski spojevi - sinteza i suodnos struktura-svojstvo (Kaitner, Branko, MZOS ) ( CroRIS)
125-1252973-2572 - Novi netoksični inhibitori korozije metala (Otmačić Ćurković, Helena, MZOS ) ( CroRIS)

Ustanove:
Prehrambeno-biotehnološki fakultet, Zagreb,
Tekstilno-tehnološki fakultet, Zagreb,
Prirodoslovno-matematički fakultet, Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb

Profili:

Avatar Url Jasna Halambek (autor)

Avatar Url Mario Cetina (autor)

Avatar Url Ivana Ugarković (autor)

Avatar Url Marijana Jukić (autor)

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com www.sciencedirect.com

Citiraj ovu publikaciju:

Jukić, Marijana; Cetina, Mario; Halambek, Jasna; Ugarković, Ivana
Synthesis, X-ray and spectroscopic analysis of 2-chloro-4-(methoxymethyl)-6-methyl-5- nitropyridine-3-carbonitrile // Journal of molecular structure, 979 (2010), 1/3; 108-114 doi:10.1016/j.molstruc.2010.06.012 (međunarodna recenzija, članak, znanstveni)
Jukić, M., Cetina, M., Halambek, J. & Ugarković, I. (2010) Synthesis, X-ray and spectroscopic analysis of 2-chloro-4-(methoxymethyl)-6-methyl-5- nitropyridine-3-carbonitrile. Journal of molecular structure, 979 (1/3), 108-114 doi:10.1016/j.molstruc.2010.06.012.
@article{article, author = {Juki\'{c}, Marijana and Cetina, Mario and Halambek, Jasna and Ugarkovi\'{c}, Ivana}, year = {2010}, pages = {108-114}, DOI = {10.1016/j.molstruc.2010.06.012}, keywords = {substituted pyridine, X-ray diffraction, IR, NMR and UV-vis spectroscopy}, journal = {Journal of molecular structure}, doi = {10.1016/j.molstruc.2010.06.012}, volume = {979}, number = {1/3}, issn = {0022-2860}, title = {Synthesis, X-ray and spectroscopic analysis of 2-chloro-4-(methoxymethyl)-6-methyl-5- nitropyridine-3-carbonitrile}, keyword = {substituted pyridine, X-ray diffraction, IR, NMR and UV-vis spectroscopy} }
@article{article, author = {Juki\'{c}, Marijana and Cetina, Mario and Halambek, Jasna and Ugarkovi\'{c}, Ivana}, year = {2010}, pages = {108-114}, DOI = {10.1016/j.molstruc.2010.06.012}, keywords = {substituted pyridine, X-ray diffraction, IR, NMR and UV-vis spectroscopy}, journal = {Journal of molecular structure}, doi = {10.1016/j.molstruc.2010.06.012}, volume = {979}, number = {1/3}, issn = {0022-2860}, title = {Synthesis, X-ray and spectroscopic analysis of 2-chloro-4-(methoxymethyl)-6-methyl-5- nitropyridine-3-carbonitrile}, keyword = {substituted pyridine, X-ray diffraction, IR, NMR and UV-vis spectroscopy} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus

Uključenost u ostale bibliografske baze podataka::


  • CA Search (Chemical Abstracts)
  • Mass Spectrometry Bulletin, PASCAL/CNRS, Scopus

Citati:

    Altmetrijski pokazatelji:


    Podijeli:





    Contrast
    Increase Font
    Decrease Font
    Dyslexic Font
    CROSBI koristi kolačiće (cookies) kako bi poboljšao funkcionalnost stranice.