Pregled bibliografske jedinice broj: 451186
Stereoselective electrochemical reduction of 8-methylene-oleandomycin
Stereoselective electrochemical reduction of 8-methylene-oleandomycin // Electrochemical and solid-state letters, 13 (2010), 4; E5-E6 doi:10.1149/1.3294500 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 451186 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Stereoselective electrochemical reduction of 8-methylene-oleandomycin
Autori
Mandić, Zoran ; Ilijaš, Marina ; Turkalj, Gordana
Izvornik
Electrochemical and solid-state letters (1099-0062) 13
(2010), 4;
E5-E6
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
8-methylene-oleandomycin ; stereoselectivity
Sažetak
The electrochemical reduction of 8-methylene-oleandomycin was investigated by cyclic voltammetry and preparative scale electrolysis. The electrochemical reduction in the exocyclic double bond predominantly gives one epimer with the estimated diastereomeric ratio of 5:1. (8S)-methyl-oleandomycin was identified as the main product of the reaction. Stereoselectivity of the electroreduction was explained by the “bottom-side” adsorption of the 8-methylene-oleandomycin through its conjugated double bond to the electrode surface.
Izvorni jezik
Engleski
Znanstvena područja
Kemija, Kemijsko inženjerstvo
POVEZANOST RADA
Projekti:
MZOS-098-0982904-2905 - Elektroaktivni filmovi za ekološki prihvatljivu konverziju i pohranu energije (Horvat-Radošević, Višnja, MZOS ) ( CroRIS)
MZOS-125-1252973-2576 - Temeljna i primijenjena istraživanja vodljivih polimera (Mandić, Zoran, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
