Pregled bibliografske jedinice broj: 448934
Tandem [4+2]/[3+2] cycloadditions of 1, 3, 4-oxadiazoles with alkenes
Tandem [4+2]/[3+2] cycloadditions of 1, 3, 4-oxadiazoles with alkenes // Mini-reviews in organic chemistry, 8 (2011), 1; 49-65 doi:10.2174/157019311793979981 (međunarodna recenzija, članak, znanstveni)
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Naslov
Tandem [4+2]/[3+2] cycloadditions of 1, 3, 4-oxadiazoles with alkenes
Autori
Margetić, Davor ; Trošelj, Pavle ; Johnston, Martin R.
Izvornik
Mini-reviews in organic chemistry (1570-193X) 8
(2011), 1;
49-65
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
cycloadditions ; oxadiazoles ; synthesis
Sažetak
A review on the tandem [4+2]/[3+2] cycloaddition reactions of 1, 3, 4-oxadiazoles with alkenes is presented. This reaction presents a powerful synthetic tool in the construction of complex polycyclic molecules in a one-pot reaction. Special attention is payed to synthesis of [n]polynorbornane and oxanorbornyl systems. In continuation, a review on the 1, 3, 4-oxadiazole reactions used in stereoselective total synthesis of alkaloids is given. Both intermolecular and intramolecular tandem [4+2]/[3+2] reactions are discussed. Stereospecificities and mechanistic rationale of various reactions are supported by quantum-chemical calculations (RHF/6-31G*).
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982933-3218 - Host-guest međudjelovanja u policikličkim sustavima (Margetić, Davor, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
