Naslov
Structure of Bis(ferrocnyl(p-tolyl)methyl) ether

Autori
Matković-Čalogović, Dubravka ; Rapić, Vladimir ; Kovač, Spomenka

Izvornik
Acta Crystallographica Section C - Crystal Structure Communications (0108-2701) C49 (1993); 226-228

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Ferrocene; crystal structure; conformation

Sažetak
C36H34Fe2O, Mr = 594, 36, monoclinic, C2/c, a = 17.316 (5), b = 11.328 (2), c = 14.837 (4)A, beta = 109.18 (3), V 0 2749 (1)A, Z = 4, Dx = 1.436 gcm-3, lambda(MoKalpha)= 0.71069A, mi = 10.8 cm-1, F(000) = 1240, room temperature, R=0.038 for 1795 unique reflections with /greater than 2sigma (I). The molecule lies on a crystallographic twofold axis which passes through the O atom. The cyclopentadienyl rings are twisted 7.6(1) from the eclipsed conformation. In the ferrocene moiety, the Fe-C distances are in the range 2.030 (5)-2.074 (4)A and C-C distances in the range 1.402(6)-1.428 (4)A. The substitution of one cyclopentadienyl ring causes some distortion within the ferrocene moiety.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA