Pregled bibliografske jedinice broj: 428506
The influence of pH value on the efficiency of imidazole based corrosion inhibitors of copper
The influence of pH value on the efficiency of imidazole based corrosion inhibitors of copper // Corrosion science, 52 (2010), 2; 398-405 doi:10.1016/j.corsci.2009.09.026 (međunarodna recenzija, članak, znanstveni)
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Naslov
The influence of pH value on the efficiency of imidazole based corrosion inhibitors of copper
Autori
Otmačić Ćurković, Helena ; Stupnišek-Lisac, Ema ; Takenouti, Hisasi
Izvornik
Corrosion science (0010-938X) 52
(2010), 2;
398-405
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
copper ; EIS ; acid inhibition ; neutral inhibition
Sažetak
The aim of this work is to establish the correlation between the solution pH and the inhibiting efficiency of two imidazole compounds (4-methyl-1-phenyl imidazole and 4-methyl-1-(p-tolyl) imidazole) in protection of copper from corrosion in chloride media. It was found that the inhibiting efficiency of both studied imidazoles enhances with the increase of the solution pH value, from about 20% in 0.5 M HCl to 92% in 0.5 M NaCl. This improvement was ascribed to stronger adsorption of neutral imidazole molecule, which can be expected at higher pH values, than that of the protonated imidazole cation, which may be expected in acid solutions.
Izvorni jezik
Engleski
Znanstvena područja
Kemijsko inženjerstvo
POVEZANOST RADA
Projekti:
MZOS-125-1252973-2572 - Novi netoksični inhibitori korozije metala (Otmačić Ćurković, Helena, MZOS ) ( CroRIS)
Ustanove:
Fakultet kemijskog inženjerstva i tehnologije, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus