аЯрЁБс>ўџ 02ўџџџ/џџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџџьЅС5@ №П0bjbjЯ2Я2 .­X­X0 џџџџџџˆЮЮЮЮЮЮЮтFFFFZ тx rrrrrrrrї љ љ љ љ љ љ $˜ RъД ЮС rrС С  ЮЮrr2 Q Q Q С NЮrЮrї Q С ї Q :Q ‹ ЮЮ‹ rf і0йЁЩF ‹ У 4H 0x ‹ ž% ž‹ ттЮЮЮЮžЮ‹ 8rrфQ ьдРrrr  ттdF; ттFINSECTICIDE POTENTIAL OF DIATOMACEOUS EARTH FROM CROATIA Zlatko KORUNIC1, Vlatka ROZMAN2, Josip HALAMIC3, Irma KALINOVIC2, Darka HAMEL4 1 Diatom Research and Consulting Inc., 14 Greenwich Dr., Guelph, ON N1H 8B8 Canada 2 Faculty of Agriculture in Osijek, Trg Sv. Trojstva 3, 31 000 Osijek, Croatia 3Croatian Geological Survey, Sachsova 2, 10000 Zagreb, Croatia 4Institute for Plant Protection in Agriculture and Forestry of Republic Croatia, Svetošimunska 25, 10040 Zagreb, Croatia Abstract Diatomaceous earth (DE) is a geological deposit consisting of the fossilized skeletons of numerous species of siliceous marine and fresh water one-cellular organisms, particularly diatoms and other algae. The skeletons are made of amorphous silicon dioxide. DE is probably the most safe and effective natural inert dust used as an insecticide. Several formulations of DE are registered and used as stored product protection insecticides around the world. The objective of the research was determination of the potential insecticide effectiveness of Croatian DE against stored products pests and the comparison of their effectiveness with the standard DE sample. One sample of the Croatian DE was selected and investigated. As a standard DE sample, the German fresh water DE SilicoSec was included into the experiment. SilicoSec formulation is registered as a grain protectant and belongs into a group of the most effective DEs in the world. The effectiveness of particle size fractions of the Croatian DE from most to least effective is: 0-20 microns (Еm), 0-45 Еm 0-150 Еm, 20-45 Еm and 45-150 Еm. The Croatian DE sample applied at 600 mg/kg containing particle size 0 - 45 Еm showed with over 90% mortality after 1 day for Cryptolestes ferrugineus, after 3 days for Sitophilus oryzae, after 7 days for Rhyzopertha dominica and after 25 days for Tribolium castaneum. SilicoSec caused 100% mortality these insects at the same or shorter time periods The effectiveness of the Croatian DE containing particles smaller than 45 Еm was equally effective against the progeny if compared with the standard DE. The authors conclude that Croatia has potential sources of DEs for ecological acceptable insecticide production and it is important to find new localities with even better sources of DEs. It can be a new safe and natural insecticide product from Croatia. 9HIXYhiyz‡ˆŠŒБнп, - I [ k l М к х ю   a p – Ÿ Ђ Ѕ Г б и й G I Ш л }Зќї№ї№ї№ї№ї№їцнеЬЦПЦеЦПЦЖЦЏЉЃЉЃЉš‘šˆ‘šššvšЉhў[ h,FІOJhў[ hШAOJhў[ hўGeOJhў[ hP'zOJhў[ hї;УOJ hў[ OJ hї;УOJ hї;У5OJhї;УCJ\aJ hї;УCJH* hї;УCJhї;УCJH*]hї;УCJaJhї;УCJ\]hї;УCJH*\] hї;УH*] hї;У]hї;У,9:‰Šн, k ф х ю 0§ћћћћћћћћљєgdў[  0ўЗатьэѓ1D -/01/0јђузЪРузЪђКДЋЁ›‡~hў[ hї;УOJ&hї;УKHOJPJaJmH nH sH tH  hў[ OJhўGehї;У5OJhў[ hўGeOJ hўGeOJ hЙYcOJhї;УOJmH sH hї;У6OJaJmH sH hї;УOJaJmH sH hї;У6OJ]aJmH sH  hї;УOJ hї;У6OJ,1hА‚. 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