Pregled bibliografske jedinice broj: 420554
Absolute stereochemistry of alloxanic acid. A configurational relay for uricase reaction
Absolute stereochemistry of alloxanic acid. A configurational relay for uricase reaction // Tetrahedron letters, 34 (1993), 29; 4679-4682 doi:10.1016/S0040-4039(00)60655-X (međunarodna recenzija, članak, znanstveni)
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Naslov
Absolute stereochemistry of alloxanic acid. A configurational relay for uricase reaction
Autori
Modrić, Nevenka ; Poje, Mirko ; Watkin, D. J. ; Edwards, A. J.
Izvornik
Tetrahedron letters (0040-4039) 34
(1993), 29;
4679-4682
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
alloxanic acid ; enantiomorphic esters ; X-ray ; (+)-(R)-alloxanic acid ; (-)-(S)-5-hydroxyisourate ; conversion ; mechanism ; allantoin
Sažetak
Alloxanic acid was resolved by means of brucine and converted into its enantiomorphic esters and amides, ethyl(-)-alloxanate whose absolute (S)-configuration was established by X-ray analysis served as configurational standard for the correlation of (+)-(R)-alloxanic acid and its precursor (-)-(S)-5-hydroxyisourate, the key uricolytic intermediate.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus