Naslov
Ferrocene Compounds. XXV. Synthesis and Characterization of Some Ferrocene-Containing Oligoamides, Their Precursors, and Analogues

Autori
Zorić, Zoran ; Rapić, Vladimir ; Lisac, Srđan ; Jukić, Marijana

Izvornik
Journal of polymer science - part A : polymer chemistry (0887-624X) 37 (1999), 1; 25-36

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
ferrocene amines; acet- and benzamides; diamides; amide-acids and amide esters; ferrocene amino acids and oligoamides; end-group analysis

Sažetak
The general method for preparation of ferrocene monoamines (5 - 7) and diamines (10, 11) starting from the corresponding quaternary ammonium iodide 3, ferrocene mono- (4), and dithiaaliphatic acids (8, 9) has been developed. Amines obtained have been characterized as acet- and benzamides (12 -15). The oligoamide precursors (16, 17, 22, 23) were synthesized by reactions of succinic or glutaric anhydride with amines (6, 7, 10, 11). Their conversion into oligoamide analogs (20, 21, 25) failed. The desired diamides (20, 21) were prepared by condensation of amines (6, 7) with alkanedioyl chlorides, (CH2)n(COCl)2 (n = 0, 1, 2, 3). Reactions of diamine 10 with succinic or glutaric anhydride gave amino acids 28 - formal monomers for the planned oligomerization. Oligomers 29 were synthesized by condensation of equimolar amounts of diamines 10 and the above mentioned alkanedioyl chlorides in dichloromethane at 0 °C. The structure of oligomers 29 was indicated from their IR and 1H NMR spectra in comparison with the model substances 12 - 28. Degree of polymerization of compounds 29 was determined by 1H NMR end-group analysis (DPn = 4-6).

Izvorni jezik
Engleski

Znanstvena područja
Kemija

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