Pregled bibliografske jedinice broj: 397169
Two tetrakis(benzoylacetonato)lanthanide species: synthesis, characterization and structures of tetrakis(benzoylacetonato)cerium(IV) and triethylammonium tetrakis(benzoylacetonato)lanthanate(III) tetrahydrate
Two tetrakis(benzoylacetonato)lanthanide species: synthesis, characterization and structures of tetrakis(benzoylacetonato)cerium(IV) and triethylammonium tetrakis(benzoylacetonato)lanthanate(III) tetrahydrate // Journal of Coordination Chemistry, 62 (2009), 16; 2698-2708 doi:10.1080/00958970902912365 (međunarodna recenzija, članak, znanstveni)
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Naslov
Two tetrakis(benzoylacetonato)lanthanide species: synthesis, characterization and structures of tetrakis(benzoylacetonato)cerium(IV) and triethylammonium tetrakis(benzoylacetonato)lanthanate(III) tetrahydrate
Autori
Stilinović, Vladimir ; Kaitner, Branko
Izvornik
Journal of Coordination Chemistry (0095-8972) 62
(2009), 16;
2698-2708
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
lanthanide; beta-diketonate; crystal structure; octacoordination
Sažetak
Tetrakis(benzoylacetonato)cerium(IV), [Ce(bzac)_4] and triethylammonium tetrakis (benzoylacetonato)lanthanate(III) tetrahydrate, [Et_3NH][La(bzac)_4] 4H_2O were prepared and characterized by TG and DCS measurements, IR spectroscopy, and X-ray structure analysis. The coordination polyhedron of cerium is a trigonal dodecahedron, while that of lanthanum is a distorted square antiprism. Thermal and spectroscopic measurements indicate that bonding of the ligand to metal is stronger in [Ce(bzac)_4] than in [La(bzac)_4]^-.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
119-1193079-3069 - Novi organski i koordinacijski spojevi - sinteza i suodnos struktura-svojstvo (Kaitner, Branko, MZOS ) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
